Degradasi Pewarna Tekstil Remazol Violet 5R Dengan Metode Elektrooksidasi Menggunakan Elektroda Grafit

Suseno Suseno, Petrus Darmawan, Peni Pujiastuti, S. Sumardiyono
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Abstract

Remazol Violet 5R textile dye degradation experiment has been carried out by electrooxidation method using graphite electrodes. The electrooxidation device consists of a plastic tub with a size (p x l x h) = 20 x 20 x 25 cm which is equipped with an electric stirrer and graphite electrodes using a used battery anode. Graphite electrodes consist of 3 pairs arranged in parallel. This dye degradation experiment was carried out using a batch system (not continuous) with variations in stirring time of 15, 30, 45, and 60 minutes, while the other variables were fixed, namely the concentration of dye 100.24 mg/liter, electrolyte NaCl 2.06 g/liter, 12 V voltage, and a stirring speed of 250 rpm. The dye solution before degradation and after degradation was measured for absorbance using a UV-Vis spectrophotometer at the maximum wavelength, to determine the percentage decrease in absorbance and optimum contact time. The experimental results showed that the percentage decrease in absorbance was constant after a contact time of 30 minutes with an absorbance of 98.36%. This indicates that the optimum contact time for the degradation of Remasol Violet 5R dye is 30 minutes. From the experiments that have been carried out, it can be concluded that the electrooxidation method using graphite electrodes can be used as an alternative waste treatment method, especially in terms of removing dyes in textile industry wastewater.
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染料降解紫罗兰5R与石墨电极的电氧化方法
采用石墨电极电氧化法对雷马唑紫5R纺织染料进行了降解实验。电氧化装置由一个尺寸为(p × l × h) = 20 × 20 × 25cm的塑料桶组成,该塑料桶配有电动搅拌器和使用废旧电池阳极的石墨电极。石墨电极由3对平行排列的电极组成。该染料降解实验采用间歇式(非连续)搅拌系统,搅拌时间分别为15、30、45、60分钟,其他变量为染料浓度100.24 mg/l,电解液NaCl 2.06 g/l,电压12 V,搅拌转速250 rpm。用紫外可见分光光度计测定降解前后染料溶液在最大波长处的吸光度,确定吸光度下降百分比和最佳接触时间。实验结果表明,接触30分钟后吸光度下降百分比不变,吸光度为98.36%。这表明,雷玛索尔紫5R染料降解的最佳接触时间为30分钟。从已进行的实验来看,石墨电极电氧化法是一种可替代的废水处理方法,特别是在去除纺织工业废水中的染料方面。
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