PESTICIDES OF MODERN CLASSES IN THE WATER AND BOTTOM SEDIMENTS OF TAGANROG BAY

V. A. Valiullin, O. Zinchuk, Yu.E. Karpushina
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Abstract

. The rivers flowing into Taganrog Bay are almost entirely surrounded by agricultural land, where the use of chemical plant protection products is inevitable. This, in turn, leads to the ingress of active ingredients (AI) of pesticides into the water and bottom sediments of the water bodies of fisheries importance. In the water and bottom sediments of Taganrog Bay, the content of 20 active ingredients of the pesticides of modern classes most widely used in agriculture in the region, the half-life of which can exceed six months, has been investigated using high-performance liquid chromatography (HPLC). As stipulated by the State Assignment, the research was being conducted throughout the year in 2014–2016 and in the spring and summer seasons in 2020. As a result of this investigation, such moderately toxic substances as clopyralid, pencycuron and tebuconazole have been identified as the main contributors to the pollution, while in 2014–2016, the main contaminant was low-toxic imidacloprid. In 2020, the total content of pesticide AIs has increased considerably both in terms of concentration and the number of substances found. However, the concentrations of pesticide AIs in the living environment of the hydrobionts in Taganrog Bay turned out to be lower than the established maximum allowable concentrations (MAC) developed for the water bodies of fisheries importance.
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塔甘罗格湾水体及底泥中现代类农药
. 流入塔甘罗格湾的河流几乎全部被农业用地包围,在那里使用化学植保产品是不可避免的。这反过来又导致农药的有效成分(AI)进入对渔业重要的水体的水和底部沉积物。采用高效液相色谱法(HPLC)研究了塔甘罗格湾(Taganrog Bay)水体和底泥中20种半衰期超过6个月的现代农药有效成分的含量。根据国家任务的规定,该研究将在2014-2016年全年以及2020年春季和夏季进行。本次调查结果确定氯吡啉、苯曲龙、戊康唑等中毒性物质为主要污染源,而2014-2016年主要污染物为低毒吡虫啉。2020年,农药人工智能的总含量在浓度和发现的物质数量方面都有大幅增加。然而,塔甘罗格湾水生生物生活环境中农药残留浓度低于渔业重要水体的最大允许浓度(MAC)。
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