Determination of the concrete heat emission during its hardening in isothermal conditions

N. V. Barannik, S. V. Kotov, E. Potapova, S. S. Malakhin
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Abstract

Introduction. The heat emission of concrete during its hardening in adiabatic conditions is typically determined according to the GOST 24316 State Satndard. This method is quite limited in research possibilities, since under the conditions of constantly increasing temperature, it appears impossible to adequately assess the influence of various components or hardening conditions on the processes occurring during the concrete hardening. The assessment of the heat emission during the isothermal hardening allows much more information about the hardening process of the studied material to be obtained. The direct determination of the concrete heat emission during hardening in isothermal conditions appears to be extremely difficult in technical aspect.Aim. The study is aimed at developing a method for determining the heat emission of the concrete in isothermal conditions.Materials and methods. The GOST 31108-2016 TsEM I 52.5N portland cement, quartz sand, crushed gabbrodiabase, and the GOST 23732-2011 mixing water were used in the study. The strength of concrete samples was determined in accordance with the GOST 10180-2012 State Standard. The TAM Air (TA Instruments) isothermal calorimeter was used for calorimetric studies.Results. As a result of the performed studies, a method for determining the concrete heat emission in isothermal conditions was developed on the basis of assessment of the heat emission during the hardening of model mixtures reflecting the composition of the studied concrete. The optimal particle size of the sand and crushed stone fractions for model mixtures comprises 0.16–0.315 mm. The heat emission during the isothermal hardening of 10 model mixtures reflecting the composition of the studied concrete grades was determined. The strength class of 10 concrete compositions differing in cement content was established. The dependence of the heat emitted by model mixtures on the strength classes of the studied concrete compositions was determined. The heat emission of model mixtures during the isothermal hardening was established to be directly dependent on the strength of the studied concrete compositions.Conclusions. The determination of the amount of heat emitted by model mixtures reflecting the composition of concrete mixtures during the isothermal hardening represents a useful cost-effective test significantly accelerating and facilitating the process of control and design of concrete compositions. 
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混凝土在等温条件下硬化过程中放热量的测定
介绍。混凝土在绝热条件下硬化过程中的放热量通常根据GOST 24316国家标准确定。这种方法的研究可能性非常有限,因为在温度不断升高的条件下,似乎不可能充分评估各种成分或硬化条件对混凝土硬化过程的影响。对等温硬化过程中热发射的评估可以获得更多关于所研究材料硬化过程的信息。在等温条件下直接测定混凝土硬化过程中的放热量在技术上是极其困难的。本研究的目的是开发一种在等温条件下测定混凝土放热的方法。材料和方法。采用GOST 23798 -2016型TsEM I 52.5N硅酸盐水泥、石英砂、破碎辉长岩、GOST 23732-2011型掺合水。混凝土试样强度按GOST 10180-2012国家标准进行测定。采用TAM Air (TA Instruments)等温量热计进行量热研究。作为所进行的研究的结果,在评估反映所研究混凝土成分的模型混合物硬化过程中的热辐射的基础上,开发了一种确定等温条件下混凝土热辐射的方法。模型混合料中砂、碎石组分的最佳粒径为0.16 ~ 0.315 mm。测定了反映所研究混凝土等级组成的10种模型混合物在等温硬化过程中的放热。建立了不同水泥掺量的10种混凝土组成的强度等级。确定了模型混合物所散发的热量与所研究混凝土成分强度等级的关系。在等温硬化过程中,模型混合物的放热量直接依赖于所研究的混凝土成分的强度。在等温硬化过程中,反映混凝土混合物组成的模型混合物释放的热量的测定是一种有用的、具有成本效益的试验,可显著加快和促进混凝土组成的控制和设计过程。
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