[Studies on application of pure titanium for cast plate].

M Sakai
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Abstract

Pure titanium produced by a commercial pure titanium casting system was studied for use as a cast plate for clinical application. The mechanical properties, elemental analysis, castability, adaptability of pure titanium and adhesion to denture base resin were investigated. The interfacial zone of the pure titanium castings was composed of a layered structure obtained by reaction with phosphate bonded Al2O3/SiO2 investment material. Vicher's hardness at 100 microns thick from the surface was higher than that in the inner part by oxidation. Cast pure titanium showed tensile strength, elongation and hardness close to those of the type III or IV dental gold alloy. The castability of pure titanium was lower than that of Co-Cr alloy and pure titanium castings also had large casting defects. Adaptability between pure titanium cast plate and the working model was satisfactory when reversible hydrocolloid impression material was used with heating-bath treatment in the refractory model. The tensile and compressive shear bonding strength of pure titanium to heat-curing or self-curing resin were similar to that of the Co-Cr alloy, and surface treatment using a solution containing 2-vol% 3-methacryloxypropyltrimethoxysilane produced a higher bonding strength than non-treatment, MKV treatment and 4-META treatment. These findings suggest that pure titanium castings produced by this system have suitable mechanical properties, adaptability and adhesion to denture base resin, and is available for cast plate in clinical application.

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纯钛在铸板中的应用研究
研究了由商业化纯钛铸造系统生产的纯钛作为临床应用的铸板。研究了纯钛的力学性能、元素分析、铸造性、适应性及与义齿基托树脂的粘附性。与磷酸键合Al2O3/SiO2熔敷材料反应得到的纯钛铸件界面区为层状结构。由于氧化作用,表面100微米处的维氏硬度高于内部部分。铸态纯钛的抗拉强度、伸长率和硬度接近于III型或IV型牙科金合金。纯钛的浇注性能低于钴铬合金,纯钛铸件也存在较大的铸造缺陷。采用可逆性水胶体压印材料对耐火材料模型进行加热浴处理时,纯钛铸板与工作模型的适应性较好。纯钛与热固化或自固化树脂的抗拉和抗压剪切结合强度与Co-Cr合金相似,表面处理采用2-vol% 3-甲基丙烯氧基丙基三甲氧基硅烷溶液,其结合强度高于未处理、MKV处理和4-META处理。结果表明,该系统生产的纯钛铸件具有良好的力学性能、适应性和对义齿基托树脂的粘附性,可用于临床铸造钢板。
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