[Adhesion of restorative resin to tooth substance. Treatment of tooth surface with aqueous solution of amino-acid derivatives and HEMA].

Abstract

Although many studies have been made on the reinforcement of the bond between tooth and restorative resin, satisfactory results have not been obtained clinically. Attempts were made to obtain such a reinforced bonding using the aqueous solution of derivatives of amino acid, either N-methacryloyl alanine (MAL) or N-acryloyl alanine (AAL), and 2-hydroxyethyl methacrylate (HEMA). Following the treatment with these surfactants, a tensile bond strength of 103 kgf/cm2 (to enamel) and 80 kgf/cm2 (to dentin) was obtained by MAL-HEMA solution, and that of 99 kgf/cm2 (to enamel) and 58 kgf/cm2 (to dentin) in the case of AAL-HEMA solution. This is considered as the result of either the etching effect of the amino acid derivatives, effect of its reactive products with hydroxyapaptite or reaction between HEMA and an organic component of tooth structure, like a collagen.