The ICP/FTS as a Source of High Resolution Atomic and Molecular Spectra

R. Engleman
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Abstract

In the early days of spectroscopy, arc sources were commonly used to obtain grating spectra of atoms and simple molecules. Since photographic detection was used, the poor stability of the arc was not a problem. Stability is a severe problem for the Fourier transform spectrometer and arcs are generally not suitable. The inductively coupled plasma (ICP), developed as a source for spectrochemical analysis, is similar in excitation to an arc, but is much cleaner and is relatively stable. Efforts have been made to exploit the ICP as a source of energetic spectra for the one meter McMath FTS of the National Solar Observatory at Kitt Peak.
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ICP/FTS作为高分辨率原子和分子光谱的来源
在光谱学的早期,电弧光源通常用于获得原子和简单分子的光栅光谱。由于使用了照相检测,弧线稳定性差就不是问题了。对于傅里叶变换光谱仪来说,稳定性是一个严重的问题,弧线通常是不合适的。电感耦合等离子体(ICP)作为光谱化学分析的一种来源,其激发方式与电弧相似,但更清洁且相对稳定。人们已经努力利用ICP作为基特峰国家太阳天文台一米麦克马斯FTS的能量光谱源。
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