Adsorption and Kinetic Studies of Methylene Blue from Aqueous Solution Using Modified Spent Tea Leaves

Mine Nur Özyaman, Sena Çağşirli, Yeliz Özüdoğru
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Abstract

In this study, methylene blue was removed from an aqueous solution using modified waste tea leaves. Temperature, pH, contact time, methylene blue concentration, and other adsorption mechanisms were studied. The characterization of the samples was performed using the FTIR and SEM analyses. The isotherm models were carrying out to analyzed the adsorption mechanisms and for representing data, the Freundlich isotherm model seemed more appropriate. The findings exhibited the highest adsorption capacity was 3.66 mg/g for the untreated biomass at 298 K, 5.46 mg/g for the 0.1 M HCl group at 318 K, and 5.98 mg/g for the 0.05 M NaOH group at 298 K. The adsorption kinetics were used and the pseudo-second-order model performed well for each group. As a natural substitute biomass for methylene blue adsorption from aqueous solution, used tea leaf residue may be employed.
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改性茶叶对水溶液中亚甲基蓝的吸附及动力学研究
在本研究中,用改性的废茶叶从水溶液中去除亚甲基蓝。研究了温度、pH、接触时间、亚甲基蓝浓度等吸附机理。利用FTIR和SEM对样品进行表征。采用等温线模型对吸附机理进行了分析,Freundlich等温线模型对数据的表示更为合适。结果表明,在298 K下,未处理生物质的吸附量最高,为3.66 mg/g,在318 K下,0.1 M HCl组的吸附量为5.46 mg/g,在298 K下,0.05 M NaOH组的吸附量为5.98 mg/g。采用拟二阶吸附动力学模型对各组分进行了较好的吸附。用过的茶叶渣作为一种天然的替代生物质,可以代替水溶液中亚甲基蓝的吸附。
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