POTENTIAL OF ILMENITE AS A SOLAR ABSORBER

G. P. D. Sousa, K. C. Gomes, Wanderley F. A. Junior, R. N. C. Duarte
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Abstract

Titanium is considered the fourth most widely used material in industry worldwide. Titanium minerals are currently being applied in various branches of industry, mainly in the field of pigmentation. Ilmenite (FeTiO3) is an iron and titanium oxide of more common and abundant occurrence, with theoretical composition of Fe (36.8%), Ti (31.6%) and O (31.6%). Having regard to the potential of titanium minerals and the abundance of ilmenite, together with the importance of validating direct applications of this ore, since the processing of titanium is still complex and expensive, it is necessary to study this mineral and the knowledge of its main characteristics. This work brings thermal, chemical and mineralogical characterizations of ilmenite, in order to know the potential of application of this ore as a solar absorbing material. The characterization techniques used were: X-ray diffraction (XRD) and Rietveld refinement for phase quantification, X-ray fluorescence (XRF), optical spectroscopy in the middle infrared region with Fourier Transformation by Transmittance (FTIR) and thermogravimetric thermal analysis (TGA). The analyzed sample obtained X-ray diffractogram, ilmenite (80.6%) and rutile (19.4%) as significant phases, corroborating the FRX results that indicated greater presence of Fe and titanium oxide in the ilmenite chemical composition under study. The TGA, DTA and DSC analyses indicated good thermal stability of the material in medium and high temperatures. The integration of the obtained data shows that the application of this ore as a precursor material of absorber films for selective purposes is considerable.
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钛铁矿作为太阳能吸收剂的潜力
钛被认为是世界上第四大最广泛使用的工业材料。钛矿物目前被应用于各个工业部门,主要是在色素沉着领域。钛铁矿(FeTiO3)是一种较为常见和丰富的铁钛氧化物,理论成分为Fe(36.8%)、Ti(31.6%)和O(31.6%)。考虑到钛矿物的潜力和钛铁矿的丰富性,以及证实这种矿石的直接应用的重要性,由于钛的加工仍然复杂和昂贵,有必要研究这种矿物并了解其主要特性。本研究对钛铁矿进行了热、化学和矿物学表征,以了解该矿石作为太阳能吸收材料的应用潜力。采用的表征技术有:x射线衍射(XRD)和Rietveld细化相定量、x射线荧光(XRF)、中红外区傅里叶透射变换(FTIR)光谱和热重热分析(TGA)。分析样品的x射线衍射图显示,钛铁矿(80.6%)和金红石(19.4%)为显著相,证实了FRX结果,表明所研究的钛铁矿化学成分中存在较多的铁和氧化钛。热重分析(TGA)、差热分析(DTA)和差热分析(DSC)表明,该材料在中高温条件下具有良好的热稳定性。综合所得数据表明,该矿石作为选择性吸收膜前驱体材料的应用是相当可观的。
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