Research in the NO/sub 2/-gas sensitive properties of polyaniline self-assembled film

Y.D. Jiang, G. Xie, D. Li, Z.M. Wu, C.H. Huang
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Abstract

Self-assembly as a novel method to prepare ultrathin functional films has drawn more and more attention in recent years. The preparation methods, structure, characterization and NO/sub 2/ gas sensitive properties of polyaniline (PAN) ultrathin films are studied in this paper. Firstly, PAN, bpolyphthalocyanine and polycation were prepared as raw materials for self-assembling PAN ultrathin films. The self-assembled PAN ultrathin films with polymeric and phthalocyanines were prepared based on doping-induced deposition effect. These films were characterized by ultraviolet/visible (UV-Vis) spectroscopy. The study on self-assembling mechanism shows that it is acids that drives the self-assembling process, which is dependent on the PAN solution property, the types of solvents and polymeric acids, the molecular weight of polymers and temperature. At last, the NO/sub 2/ gas sensitive properties is studied in this paper.
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聚苯胺自组装膜的NO/ sub2 /-气敏性能研究
自组装作为一种制备超薄功能薄膜的新方法近年来受到越来越多的关注。研究了聚苯胺(PAN)超薄膜的制备方法、结构、表征及其NO/亚2/气敏性能。首先,以聚丙烯腈、聚酞菁和聚阳离子为原料制备自组装PAN超薄膜。利用掺杂诱导沉积效应制备了聚合物和酞菁自组装PAN超薄膜。用紫外/可见(UV-Vis)光谱对这些薄膜进行了表征。对自组装机理的研究表明,驱动自组装过程的是酸,这与PAN溶液的性质、溶剂和聚合酸的类型、聚合物的分子量和温度有关。最后,对该材料的NO/sub - 2/气敏性能进行了研究。
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