Thermally stimulated depolarization processes in zirconia toughened alumina ceramics

Peng Zhang, Jianying Li, H. Jin, Hao Zhang
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引用次数: 2

Abstract

In this paper, the zirconia toughened alumina (ZTA) ceramics were fabricated by pressureless sintering method. Dielectric relaxation characteristics of both alumina and ZTA ceramics were investigated using thermally stimulated depolarization current (TSDC) method and the relaxation parameters were calculated from the experimental TSDC curves. In addition, the relationship between zirconia doping and dielectric relaxation properties was analyzed. The results showed that doping of zirconia can affect the defect dipoles distributions in ZTA ceramics, and introduces a new relaxation peak at 478K. This new relaxation process may be attributed to the reorientation of dipoles of dopant and oxygen vacancy pairs generated in cubic zirconia grains.
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氧化锆增韧氧化铝陶瓷的热激退极化过程
本文采用无压烧结法制备了氧化锆增韧氧化铝(ZTA)陶瓷。采用热激去极化电流(TSDC)法研究了氧化铝和ZTA陶瓷的介电弛豫特性,并根据实验TSDC曲线计算了弛豫参数。此外,还分析了氧化锆掺杂与介质弛豫性能的关系。结果表明,氧化锆的掺杂影响了ZTA陶瓷中缺陷偶极子的分布,并在478K处引入了新的弛豫峰。这种新的弛豫过程可能归因于在立方氧化锆颗粒中产生的掺杂物偶极子和氧空位对的重定向。
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