Comparative study on enhanced oil recovery effect of amphiphilic nanomaterials - Experiment and mechanism Investigation

Erdong Yao, Yuan Li, Bojun Li, Lianqi Sheng, Kun Zhang, Guolin Yu, Fu-jian Zhou
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Abstract

Due to the transcendental property of nanoparticle, nanoparticle fluid flooding becomes one of the enhanced oil recovery (EOR) technique, which had played a significant role in tight oil exploitation in the worldwide scale recent years. In particular, the amphiphilic nanomaterials can greatly increase the oil recovery.To provide some guidance in selecting nanomaterials for flooding, 3 kinds of amphiphilic nanomaterials, including silicon dioxide (SiO2), graphene oxide (GO) and molybdenum disulfide (MoS2), are chosen to serve as object of the study. In lab, the physical properties were systematically characterized and flooding was conducted. Further, the morphology character of nanomaterials was placed extra emphasis and the mechanisms of EOR were also studied. The purpose was to find the link between the morphology of nanomaterials and EOR. Flooding experiment revealed that MoS2 were able to enhance the oil recovery by approximately 11%, which were better that of the others. From the above, it can be inferred that spherical materials have a “point-to-surface” contact at multiphase interfaces, while sheet materials can achieve a “surface-to-surface” contact with a higher interfacial activity. In addition, the film-climbing characteristics of amphiphilic nanomaterials were found in the experiment, which may be one of the potential reasons for enhanced oil recovery.
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两亲性纳米材料提高采收率效果的对比研究——实验与机理研究
由于纳米颗粒的超越性,纳米颗粒流体驱油技术成为提高采收率的技术之一,近年来在世界范围内致密油开发中发挥了重要作用。特别是两亲性纳米材料可以大大提高采收率。为了对驱油纳米材料的选择提供一定的指导,以二氧化硅(SiO2)、氧化石墨烯(GO)和二硫化钼(MoS2) 3种两亲性纳米材料为研究对象。在实验室中,系统地表征了其物理性质并进行了驱油。在此基础上,重点研究了纳米材料的形貌特征和提高采收率的机理。目的是寻找纳米材料的形貌与提高采收率之间的联系。驱油实验表明,二硫化钼可提高采收率约11%,优于其他驱油剂。由此可以推断,球形材料在多相界面处具有“点对面”接触,而片状材料可以实现“面对面”接触,界面活性更高。此外,实验还发现了两亲性纳米材料的爬膜特性,这可能是提高采收率的潜在原因之一。
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