Characterization of a Coal Shale from Marcel Mining as Raw Material for Geopolymer Manufacturing

K. Korniejenko, B. Figiela, K. Pławecka, A. Bulut, B. Şahin, G. Azizağaoğlu, M. Łach
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Abstract

: Implementing the idea of a circular economy is one way to reduce carbon emissions and, at the same time, the consumption of natural resources. The use of mining waste as a raw material helps meet the growing demand for construction materials with a smaller carbon footprint. The article shows the possibility of using a coal shale from Marcel mining to create new eco-friendly materials, geopolymers. The main aim of the presented research includes characteristics of raw material and synthesis of geopolymers based on mining waste (coal shale from Marcel mining) and next, investigations of the obtained materials. Geopolymer was prepared using a sodium activator plus milled and calcinated precursor materials. In this study, the following research methods were used: particle size analysis, XRD analysis, mechanical properties tests (compressive and bonding strength), and microstructure analysis—scanning electron microscopy. The results show potential for the extraction of waste from the Marcel company to obtain material for advanced applications in the geopolymerization process. The material had a compressive strength of 12.7 MPa and a bending strength of 3.4 MPa, which makes it possible for use in construction applications such as various types of foundations, walls, columns, lintels, terraces, stairs, ceilings, small building elements, and small architecture. The proposed process could be a promising alternative to current methods of managing waste rock, in particular hard coal mining.
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马塞尔矿煤页岩制备地聚合物原料的表征
实施循环经济的理念是减少碳排放,同时减少自然资源消耗的一种方式。使用采矿废料作为原材料有助于满足对建筑材料日益增长的需求,同时减少碳足迹。这篇文章展示了利用马塞尔煤矿的煤页岩来制造新的环保材料——地聚合物的可能性。本研究的主要目的是研究以马塞尔煤矿的煤页岩为原料合成地聚合物的原料特性,并对所得材料进行研究。以钠为活化剂,再加上粉碎和煅烧的前驱体材料制备地聚合物。本研究采用了以下研究方法:粒度分析、XRD分析、力学性能测试(抗压和结合强度)、微观结构分析-扫描电镜。结果表明,从马塞尔公司提取的废物有潜力获得在地聚合过程中先进应用的材料。该材料的抗压强度为12.7 MPa,抗弯强度为3.4 MPa,这使得它可以用于建筑应用,如各种类型的基础,墙壁,柱子,门楣,露台,楼梯,天花板,小型建筑元素和小型建筑。拟议的过程可能是目前管理废石,特别是硬煤开采方法的一个有希望的替代方法。
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