Ya. I. Kurys, I. B. Bychko, O. O. Pariiska, O. Z. Didenko, D. O. Mazur, P. E. Strizhak, V. G. Koshechko, V. D. Pokhodenko
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引用次数: 0
Abstract
Nitrogen-doped carbon, which is characterized by a large surface area and the presence of micro- and mesopores, has been obtained by pyrolysis of polyaniline (emeraldine base) in a reducing atmosphere. It is found that the surface layer of such material contains nitrogen in pyridinic, pyrrolic, and quaternary configurations, as well as hydroxyl and carbonyl groups. It is shown that carbonized polyaniline reveals catalytic properties in the processes of gas-phase and liquid-phase hydrogenation with molecular hydrogen of organic substrates containing C=C double bond and nitro group (ethylene, α-methylstyrene, p-nitrotoluene) are revealed.
期刊介绍：
Theoretical and Experimental Chemistry is a journal for the rapid publication of research communications and reviews on modern problems of physical chemistry such as:
a) physicochemical bases, principles, and methods for creation of novel processes, compounds, and materials;
b) physicochemical principles of chemical process control, influence of external physical forces on chemical reactions;
c) physical nanochemistry, nanostructures and nanomaterials, functional nanomaterials, size-dependent properties of materials.
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