Dual‐strategy modification on P2‐Na0.67Ni0.33Mn0.67O2 realizes stable high‐voltage cathode and high energy density full cell for sodium‐ion batteries

IF 18.7 1区 材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY SusMat Pub Date : 2023-02-01 DOI:10.1002/sus2.115
Guanglin Wan, Bo Peng, Liping Zhao, Feng Wang, Lai Yu, Rong Liu, Genqiang Zhang
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Abstract

A dual strategy of Mg2+ doping integrated with ZrO2 surface modification is applied on P2-Na0.67Ni0.33Mn0.67O2 to optimize its electrochemical performance. The damaged P2–O2 phase transition as well as side reactions between cathode and electrolyte are both suppressed after dual-strategy modification, thus realizing stable high-voltage cathode and high energy density full cell for sodium ion batteries.
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对P2‐Na0.67Ni0.33Mn0.67O2进行双策略改性,实现了钠离子电池稳定的高压正极和高能量密度全电池
采用Mg2+掺杂与ZrO2表面改性相结合的双重策略对P2-Na0.67Ni0.33Mn0.67O2进行了电化学性能优化。双策略改性抑制了受损的P2-O2相变和阴极与电解质的副反应,实现了钠离子电池稳定的高压阴极高能量密度全电池。
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期刊介绍: SusMat aims to publish interdisciplinary and balanced research on sustainable development in various areas including materials science, engineering, chemistry, physics, and ecology. The journal focuses on sustainable materials and their impact on energy and the environment. The topics covered include environment-friendly materials, green catalysis, clean energy, and waste treatment and management. The readership includes materials scientists, engineers, chemists, physicists, energy and environment researchers, and policy makers. The journal is indexed in CAS, Current Contents, DOAJ, Science Citation Index Expanded, and Web of Science. The journal highly values innovative multidisciplinary research with wide impact.
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