Synthesis and structural study of conductive polyaniline using a new method for average mass determination with ultraviolet spectroscopy

IF 0.5 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY International Journal of Materials & Product Technology Pub Date : 2023-01-01 DOI:10.1504/ijmpt.2023.133051
Hattab Youcef, Benharrats Nassira
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Abstract

In recent years, many advances have been made in the understanding of the conduction mechanisms of conductive polymers. Several reports have highlighted the role of the best characterisation. However, a number of questions remain unanswered. One of the problems is the easy specification of the average mass of polyaniline by UV analyse. The first synthesis of the emeraldine salt is a form doped with hydrochloric acid, and the emeraldine base is the dedoped form of PANI. Then, it was characterised by IR spectroscopy, UV/visible, and compared by GPC chromatography. After calculating the average mass of PANI, it was concluded that new easy UV-visible method is approved by GPC results.
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紫外分光光度法测定导电聚苯胺平均质量的合成及结构研究
近年来,对导电聚合物导电机理的认识取得了许多进展。有几份报告强调了最佳描述的作用。然而,仍有许多问题没有得到解答。其中一个问题是紫外分析容易确定聚苯胺的平均质量。第一次合成的祖母绿盐是掺杂盐酸的形式,祖母绿碱是聚苯胺的脱掺杂形式。然后用红外光谱、紫外/可见光谱对其进行表征,并用GPC色谱对其进行比较。通过计算聚苯胺的平均质量,GPC结果表明,新的简便紫外可见法是可行的。
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来源期刊
International Journal of Materials & Product Technology
International Journal of Materials & Product Technology 工程技术-材料科学:综合
CiteScore
0.80
自引率
0.00%
发文量
61
审稿时长
8 months
期刊介绍: The IJMPT is a refereed and authoritative publication which provides a forum for the exchange of information and ideas between materials academics and engineers working in university research departments and research institutes, and manufacturing, marketing and process managers, designers, technologists and research and development engineers working in industry.
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