Fate and transport analysis of a Dowtherm–A chemical release event

IF 1 4区 工程技术 Q4 ENGINEERING, CHEMICAL Process Safety Progress Pub Date : 2023-11-10 DOI:10.1002/prs.12552
Kotaiba Abugazleh, Hashim Ali, Kwangkook Jeong, Mohammad Abutayeh
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Abstract

Abstract A hypothetical chemical release of Dowtherm–A into the environment was simulated using a chemodynamics code. The chemical release was assumed to come from a concentrating solar power plant adjacent to Lake Tahoe. Dowtherm–A is viscous water‐insoluble nonvolatile oil found mostly in liquid form at standard temperature and pressure; however, trace amounts slowly diffuse into the three environmental phases: air, water, and soil. It is a commercial eutectic binary mixture of diphenyl oxide and biphenyl—both are toxic and flammable. Therminol VP–1 is another commercial heat transfer oil made by Eastman that is essentially the same oil as Dowtherm–A made by Dow: same constituents at equal proportions. Therefore, the results reported in this study apply to both fluids. Solar thermal power generation represents a clean source of energy that almost uses no fossil fuels and thus does not emit any greenhouse gases. However, the oil employed in those solar thermal power plants is dangerous and should be carefully handled to avoid leakage.
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Dowtherm-A化学物质释放事件的命运和运输分析
使用化学动力学代码模拟了Dowtherm-A在环境中的化学释放。据推测,化学物质的释放来自太浩湖附近的一个集中太阳能发电厂。Dowtherm-A是一种粘性水不溶性非挥发性油,在标准温度和压力下以液体形式存在;然而,微量会慢慢扩散到三个环境阶段:空气、水和土壤。它是氧化二苯和联苯的商业共晶二元混合物,两者都是有毒和易燃的。Therminol VP-1是伊士曼公司生产的另一种商业导热油,本质上与陶氏公司生产的Dowtherm-A相同:成分相同,比例相同。因此,本研究报告的结果适用于这两种流体。太阳能热发电是一种清洁能源,几乎不使用化石燃料,因此不排放任何温室气体。然而,这些太阳能热发电厂使用的油是危险的,应该小心处理,以避免泄漏。
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来源期刊
Process Safety Progress
Process Safety Progress 工程技术-工程:化工
CiteScore
2.20
自引率
10.00%
发文量
99
审稿时长
6-12 weeks
期刊介绍: Process Safety Progress covers process safety for engineering professionals. It addresses such topics as incident investigations/case histories, hazardous chemicals management, hazardous leaks prevention, risk assessment, process hazards evaluation, industrial hygiene, fire and explosion analysis, preventive maintenance, vapor cloud dispersion, and regulatory compliance, training, education, and other areas in process safety and loss prevention, including emerging concerns like plant and/or process security. Papers from the annual Loss Prevention Symposium and other AIChE safety conferences are automatically considered for publication, but unsolicited papers, particularly those addressing process safety issues in emerging technologies and industries are encouraged and evaluated equally.
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