Self-Healing Coatings Consisting of an Outer Electrodeposited Epoxy Resin Layer and an Inner Porous Anodic Oxide Layer with Healing Agents for the Corrosion Protection of Al Alloys

Rin Takada, Kota Hirasawa, Hideaki Takahashi, Makoto Chiba
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Abstract

Recently, new surface treatments for the corrosion protection of Al alloys by forming self-healing layers have attracted the attention of many researchers. The authors of this paper have previously developed self-healing polyurethane coatings with micro-capsules containing healing agents and porous anodic oxide films filled with healing agents. In this study, self-healing coatings consisting of an outer electrodeposited epoxy resin layer and an inner porous anodic oxide layer with healing agents were developed for the corrosion protection of Al alloys. The corrosion protection abilities of the self-healing coating were shown in Cu2+/Cl− solutions after damaging with indenters and were affected by freezing treatments and the tip angles of the indenter.
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由外电沉积环氧树脂层和内多孔阳极氧化层组成的自修复涂层,具有修复剂,用于铝合金的腐蚀保护
近年来,通过形成自愈层来保护铝合金腐蚀的新表面处理方法引起了许多研究者的关注。本论文的作者先前已经开发了自修复聚氨酯涂料,其微胶囊含有愈合剂和多孔阳极氧化膜填充愈合剂。在本研究中,开发了一种由外电沉积环氧树脂层和内带愈合剂的多孔阳极氧化层组成的自修复涂层。自愈涂层在Cu2+/Cl−溶液中表现出受压头损伤后的防腐能力,并受冷冻处理和压头尖端角度的影响。
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