Sustainable composites of eco-friendly polyethylene reinforced with eggshells and bio-calcium carbonate

IF 1 4区 化学 Q4 POLYMER SCIENCE Polimeros-ciencia E Tecnologia Pub Date : 2023-01-01 DOI:10.1590/0104-1428.20220108
Kássia Peçanha Vieira, Alexandra Augusta Reichert, Gabriel Monteiro Cholant, Dielen Marin, Cesar Augusto Gonçalves Beatrice, Amanda Dantas de Oliveira
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Abstract

This work aimed to obtain and analyze composite materials made from green polyethylene and calcium carbonate extracted from chicken eggshells. The shells were collected and prepared for later extraction of calcium carbonate. With the X-ray diffraction analysis it was possible to confirm that both the in natura reinforcement and the calcined one, have the same polymorph mineral (calcite). With regard to thermal behavior, compounds with in natura reinforcement showed greater mass loss due to the moisture contained in them. The results showed a significant increase in Young’s moduli of the composites compared to the pure polymer. The scanning electron microscopy showed good dispersion and adhesion between the reinforcement materials and matrix. In view of the results, eggshells have the potential to be used as fillers, where greater rigidity is required. Since these materials come from a waste material, with low cost, their use becomes even more viable.
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可持续复合材料的环保聚乙烯增强与蛋壳和生物碳酸钙
这项工作旨在获得并分析由绿色聚乙烯和从鸡蛋壳中提取的碳酸钙制成的复合材料。收集贝壳,为提取碳酸钙做准备。通过x射线衍射分析,可以证实天然增强和煅烧增强具有相同的多晶矿物(方解石)。在热性能方面,含有非天然增强剂的化合物由于其中含有水分而表现出更大的质量损失。结果表明,与纯聚合物相比,复合材料的杨氏模量显著增加。扫描电镜显示增强材料与基体之间具有良好的分散和粘附性。鉴于这些结果,蛋壳有可能被用作需要更大刚度的填料。由于这些材料来自废料,成本低,它们的使用变得更加可行。
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来源期刊
Polimeros-ciencia E Tecnologia
Polimeros-ciencia E Tecnologia 化学-高分子科学
CiteScore
2.00
自引率
0.00%
发文量
14
审稿时长
6 months
期刊介绍: Polímeros is a quarterly publication of the Associação Brasileira de Polímeros - ABPol (Brazilian Polymer Association), which publishes Review Articles, Original Articles and Short Communications, disclosing advances in the knowledge of Polymer Science and Technology.
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