Physical, Optical, and Photoluminescence Properties of Cr ₂ O ₃ in Borosilicate Glasses

IF 0.7 4区工程技术 Q4 ENGINEERING, ELECTRICAL & ELECTRONIC Integrated Ferroelectrics Pub Date : 2023-09-29 DOI:10.1080/10584587.2023.2234583

N. Singkiburin, N. Mahingsa, N. Srisittipokakun, N. Luewarasirikul, R. Rajaramakrishna, S. Kothan, C. Kedkaew, J. Kaewkhao

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Abstract

AbstractThe glass samples (35-x)B2O3:35SiO2:12Na2O:7.9CaO:0.1Sb2O3:10BaO:xCr2O3 with a variation of Cr2O3 content were successfully fabricated and characterized for solid-state lighting material applications. The results showed the most suitable composition within the range of study at 0.02 mol% of Cr2O3. This composition gave higher reflection loss (RL), lower oxide polarizability, and lower molar refractivity. The Commission International de I'Eclairage (CIE) chromaticity coordinates confirmed a strong orange color emission. Hence, this suggests that the 0.02 mol% Cr2O3 glass is a good candidate and cost-effective for orange-emitting solid-state lighting material applications. This study will be a useful literature source for further development in this field.Keywords: Borosilicate glassCr2O3 concentrationluminescence propertiesTanabe–Sugano diagram AcknowledgmentsJ. Kaewkhao and N. Srisittipokakun would like to thanks Thailand Science Research and Innovation (TSRI) for partially supporting this research.Disclosure StatementNo potential conflict of interest was reported by the author(s).Additional informationFundingThis research has been funded by Research Council of Thailand (NRCT) and Gemories Thailand Co. Ltd. (Project number N41A650403). This research was partially supported by Chiang Mai University.

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Cr 2o3在硼硅酸盐玻璃中的物理、光学和光致发光性质

摘要成功制备了具有不同Cr2O3含量的(35-x)B2O3:35SiO2:12Na2O:7.9CaO:0.1Sb2O3:10BaO:xCr2O3玻璃样品，并对其进行了表征。结果表明，在研究范围内，Cr2O3含量为0.02 mol%是最合适的。该成分具有较高的反射损耗(RL)、较低的氧化物极化率和较低的摩尔折射率。国际照明委员会(CIE)色度坐标证实了强烈的橙色发射。因此，这表明0.02 mol% Cr2O3玻璃是一个很好的候选，具有成本效益的橙色发射固态照明材料应用。本研究将为该领域的进一步发展提供有益的文献来源。关键词:硼硅酸盐玻璃;cr2o3浓度;发光特性;Kaewkhao和N. Srisittipokakun感谢泰国科学研究与创新(TSRI)对这项研究的部分支持。披露声明作者未报告潜在的利益冲突。本研究由泰国研究委员会(NRCT)和Gemories Thailand Co. Ltd.(项目编号N41A650403)资助。这项研究得到了清迈大学的部分支持。

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来源期刊

Integrated Ferroelectrics 工程技术-工程：电子与电气

CiteScore

1.40

自引率

0.00%

发文量

179

审稿时长

3 months

期刊介绍： Integrated Ferroelectrics provides an international, interdisciplinary forum for electronic engineers and physicists as well as process and systems engineers, ceramicists, and chemists who are involved in research, design, development, manufacturing and utilization of integrated ferroelectric devices. Such devices unite ferroelectric films and semiconductor integrated circuit chips. The result is a new family of electronic devices, which combine the unique nonvolatile memory, pyroelectric, piezoelectric, photorefractive, radiation-hard, acoustic and/or dielectric properties of ferroelectric materials with the dynamic memory, logic and/or amplification properties and miniaturization and low-cost advantages of semiconductor i.c. technology.

Physical, Optical, and Photoluminescence Properties of Cr 2 O 3 in Borosilicate Glasses

Abstract

Physical, Optical, and Photoluminescence Properties of Cr ₂ O ₃ in Borosilicate Glasses