Photoplastic effect in MgO single crystals

IF 1.3 4区 材料科学 Q3 MATERIALS SCIENCE, CERAMICS Journal of the Ceramic Society of Japan Pub Date : 2023-10-01 DOI:10.2109/jcersj2.23060
Yu Ogura, Yuki Tsuchiya, Sena Hoshino, Tatsuya Yokoi, Katsuyuki Matsunaga
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Abstract

The photoplastic effect, phenomena that flow stress and/or hardness change by light illuminations, has been known mainly in II–VI compound semiconductors. In this study, it was revealed for the first time that magnesium oxide (MgO) single crystals exhibit increase in flow stress by light illumination, namely, the positive photoplastic effect. Scanning transmission electron microscope (STEM) observations demonstrated that the plastic deformation of MgO is realized by generation of glide dislocations on the slip system of {110}〈110〉. Therefore, the observed positive photoplastic effect of MgO is likely due to interactions of the glide dislocations and photo-excited carriers. According to the theoretical calculations, individual dislocations in MgO had a specific band structure that differs from the bulk. This also indicates possible interactions between dislocations and carriers. It is expected that light illumination can reduce dislocation mobility in MgO, leading to the increase in flow stress under light illuminations.
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MgO单晶的光塑性效应
光塑性效应,即流动应力和/或硬度随光照变化的现象,主要是在II-VI化合物半导体中发现的。本研究首次揭示了氧化镁(MgO)单晶在光照下表现出流动应力的增加,即正光塑性效应。扫描透射电镜(STEM)观察表明,MgO的塑性变形是通过在{110}< 110 >滑移系上产生滑移位错实现的。因此,观察到的MgO的正光塑性效应可能是由于滑动位错和光激发载流子的相互作用。根据理论计算,MgO中的单个位错具有不同于体的特定能带结构。这也表明位错和载流子之间可能存在相互作用。预计光照可以降低MgO中的位错迁移率,从而导致光照下流动应力的增加。
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来源期刊
Journal of the Ceramic Society of Japan
Journal of the Ceramic Society of Japan 工程技术-材料科学:硅酸盐
CiteScore
2.10
自引率
18.20%
发文量
170
审稿时长
2 months
期刊介绍: The Journal of the Ceramic Society of Japan (JCS-Japan) publishes original experimental and theoretical researches and reviews on ceramic science, ceramic materials, and related fields, including composites and hybrids. JCS-Japan welcomes manuscripts on both fundamental and applied researches.
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