Colossal permittivity and ultralow dielectric loss in Nb-doped SrTiO 3 ceramics

Abstract

Defect engineering has been applied to prepare materials with modifiable dielectric properties. SrTiNb_xO₃ (x=0, 0.003, 0.006, 0.009, 0.012) ceramics were synthesized using the traditional solid-state reaction method and sintered in a reducing atmosphere. All samples show excellent dielectric properties with giant permittivity (>3.5×10⁴) and low dielectric loss (<0.01). SrTiNb_0.003O₃ ceramic exhibits a colossal permittivity of 4.6×10⁴ and an ultralow dielectric loss of 0.005 (1 kHz, room temperature) as well as great temperature stability in the range of -60～160℃. The mechanism of the presented CP properties is investigated by conducting XPS and analyzing activation energies. The results indicate that the introduction of Nb⁵⁺ and the reducing sintering atmosphere together generated the formation of Ti³⁺ and V ^∙∙_O. These defects further form Ti'_Ti−V ^∙∙_O−Ti'_Ti defect dipoles, contributing to the coexisting giant permittivity and low dielectric loss in STN ceramics.