Effect of recycled powder on the yield stress of cement paste with varied superplasticizers

Zhen Li, Cheng Yu, Min Qiao, Weixiao Xie, Jinyao Yu
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Abstract

Abstract The influence of superplasticizer on the yield stress of cement pastes with recycled powder (RP) was examined in the study. Four superplasticizers were used to obtain the similar fluidity by adjusting the dosage. The results show that the 10% RP decreases the yield stress of paste compared to the reference paste at the same fluidity, but 20% and 30% RP increases the yield stress, ranging from 11 to 599%. The superplasticizer with adsorptive group of phosphate-type minimizes the yield stress of paste than that of polycarboxylate -type, but it made a significant increment in yield stress as the incorporating of RP increased. Besides, the polycarboxylate superplasticizer with the higher molecular weight of side chain and charge density led to lower yield stress. Based on the Yodel model, the yield stress of paste with RP was analyzed by the polymer adsorption and particle packing density of particles to reveal the influence of RP with different superplasticizers on the colloidal interaction and contact network among the particles. The packing density of particles with recycled powder was a little higher than the reference paste, but the higher fraction of fine particles made a stronger PSD effect, which improved the particle contact interaction. On the other hand, due to the higher polymer adsorption of recycled powder than cement, especially for superplasticizer with phosphate group, the average surface coverage was increased, which extended the separation distance, so that colloidal interaction among particles was weaken.
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再生粉对不同高效减水剂水泥浆体屈服应力的影响
摘要研究了高效减水剂对再生粉水泥浆体屈服应力的影响。采用四种高效减水剂,通过调整用量可获得相似的流动性。结果表明:在相同流动度下,10% RP与对照膏体相比,降低了膏体的屈服应力,而20%和30% RP使膏体的屈服应力增大,幅度在11% ~ 599%之间;磷酸盐型高效减水剂比聚羧酸型高效减水剂的屈服应力最小,但随着RP加入量的增加,其屈服应力显著增加。此外,侧链分子量和电荷密度较高的聚羧酸酯型高效减水剂降低了屈服应力。基于Yodel模型,从聚合物吸附和颗粒堆积密度两方面分析了RP膏体的屈服应力,揭示了RP与不同高效减水剂对颗粒间胶体相互作用和接触网络的影响。再生粉颗粒的堆积密度略高于参考膏体,但较高的细颗粒比例使PSD效应更强,从而改善了颗粒的接触相互作用。另一方面,由于再生粉的聚合物吸附性高于水泥,特别是含磷酸基团的高效减水剂,增加了平均表面覆盖率,延长了分离距离,使颗粒间的胶体相互作用减弱。
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