Investigating the Effect of Cashew Nut Oil (Anacardium occidentale) Biodiesel on Corrosion of Metals

P. O. Akusu, O. T. Ogunmodede, E. Erhuen, G. T. Buluku
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Abstract

The transition from fossil fuel to clean and renewable fuel is a burning issue in the global space as at present. In addition to other source of energy, renewable liquid fuels such as biodiesel are providing solution to this surging global need. Just like fossil fuels, these renewable fuels come with their own challenges of which corrosion is prime. In this study the corrosion behaviour of metals in cashew nut oil biodiesel was conducted. Oil extracted from Cashew nuts was characterized for acid value free fatty acid and fatty acid profile. The oil was further trans esterified into biodiesel and fuel properties were characterized. Corrosion test for selected metals in biodiesel using mass loss method was also conducted. The acid value and free fatty acid for the oil was observed to be 5.61 mg/g KOH and 2.26 mg/g KOH respectively. The fatty acid profile was observed to be more of monounsaturated fatty acid especially Oleic acid (68.2 wt %) for biodiesel. The corrosion test showed copper metals and mild steel have higher corrosion rate of 0.02896 mm/y and 0.02617 mm/y respectively. Hence the corrosion pattern of metal in cashew nut oil biodiesel is slightly higher than other edible oil biodiesel.
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腰果油(Anacardium occidentale)生物柴油对金属腐蚀的影响
从化石燃料到清洁和可再生燃料的过渡是目前全球空间的一个紧迫问题。除了其他能源来源外,生物柴油等可再生液体燃料正在为这一激增的全球需求提供解决方案。就像化石燃料一样,这些可再生燃料也有自己的挑战,其中腐蚀是首要问题。研究了金属在腰果油生物柴油中的腐蚀行为。对腰果油的酸值、游离脂肪酸和脂肪酸谱进行了表征。将该油进一步反酯化制备生物柴油,并对其燃料特性进行了表征。用质量损失法对生物柴油中选定的金属进行了腐蚀试验。油的酸值和游离脂肪酸分别为5.61 mg/g KOH和2.26 mg/g KOH。脂肪酸谱主要为单不饱和脂肪酸,尤其是油酸(68.2%)。腐蚀试验表明,铜金属和低碳钢的腐蚀速率较高,分别为0.02896 mm/y和0.02617 mm/y。因此腰果油生物柴油中金属的腐蚀模式略高于其他食用油生物柴油。
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