JOANNA WOJTASZ-MUCHA, MERIMA HASANI, HANS THELIANDER
{"title":"Dissolution of wood components during hot water extraction of spruce","authors":"JOANNA WOJTASZ-MUCHA, MERIMA HASANI, HANS THELIANDER","doi":"10.32964/tj22.5.329","DOIUrl":null,"url":null,"abstract":"The purpose of this study was to investigate the autohydrolysis of softwood, which is the main chemical operation in both hot water extraction and steam explosion. Control of the process and monitoring its course were ensured by the careful choice of experimental setup and conditions: a milled spruce material was extracted in a small flow-through reactor to minimize degradation of the dissolved material and to enable analysis of the resulting liquors extracted at selected time points. The obtained liquid and solid fractions were analyzed for sugar composition and acetic acid concentration. The results showed that partially degraded hemicelluloses were extracted; hemicelluloses side chains were cleaved off and detected as monomers, while deacetylation was limited. Chain scissions of cellulose were observed as a result of autohydrolysis.","PeriodicalId":22255,"journal":{"name":"Tappi Journal","volume":null,"pages":null},"PeriodicalIF":0.6000,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Tappi Journal","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.32964/tj22.5.329","RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"MATERIALS SCIENCE, PAPER & WOOD","Score":null,"Total":0}
引用次数: 0
Abstract
The purpose of this study was to investigate the autohydrolysis of softwood, which is the main chemical operation in both hot water extraction and steam explosion. Control of the process and monitoring its course were ensured by the careful choice of experimental setup and conditions: a milled spruce material was extracted in a small flow-through reactor to minimize degradation of the dissolved material and to enable analysis of the resulting liquors extracted at selected time points. The obtained liquid and solid fractions were analyzed for sugar composition and acetic acid concentration. The results showed that partially degraded hemicelluloses were extracted; hemicelluloses side chains were cleaved off and detected as monomers, while deacetylation was limited. Chain scissions of cellulose were observed as a result of autohydrolysis.
期刊介绍：
An internationally recognized technical publication for over 60 years, TAPPI Journal (TJ) publishes the latest and most relevant research on the forest products and related industries. A stringent peer-review process and distinguished editorial board of academic and industry experts set TAPPI Journal apart as a reliable source for impactful basic and applied research and technical reviews.
Available at no charge to TAPPI members, each issue of TAPPI Journal features research in pulp, paper, packaging, tissue, nonwovens, converting, bioenergy, nanotechnology or other innovative cellulosic-based products and technologies. Publishing in TAPPI Journal delivers your research to a global audience of colleagues, peers and employers.
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