Removal of Heavy Metals from Waste Water by Using Bi-Mg Bimetallic Nanoparticles Incorporated with Orange Peels

Ishrat Fatima, Nida Yasmeen, None Momina, Muhammad Irfan, Inam Ullah, Rimsha Afzal, Ayesha Noor, Aneela Shaheen
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Abstract

Plant-mediated synthesis of the nanoparticles has attracted significant interest because of their biocompatible properties. Bimetallic nanoparticles comprise two different types of metals that play a significant role in wastewater. Bimetallic nanoparticles possess a greater surface area, increasing their adsorption than monometallic nanoparticles. In this study, synthesis and the adsorption behaviour of Bi-Mg bimetallic nanoparticles and their removal efficiency toward heavy metals (cadmium, lead, zinc) from wastewater is observed. Synthesis of bimetallic nanoparticles by natural resources (plant extract) is more significant than conventional methods because they are environment friendly, reliable, nontoxic and least expensive. Plant extract obtained from biomass wastes like roots, flowers, leaves and fruit peels is composed of novel secondary metabolites like terpenoids, flavonoids and alkaloids that act as stabilizing and reducing agents. Different techniques like SEM, EDX and XRD were used to analyze the morphology, composition and size of synthesized nanoparticles. The removal of heavy metals depends on the pH, dosage of adsorbent and initial concentration of the metals. The results showed that the plant-mediated synthesized nanoparticles could act as an efficient adsorbent to remove heavy metals from wastewater.
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双金属纳米颗粒与橘皮复合去除废水中重金属的研究
由于其生物相容性,植物介导的纳米颗粒合成引起了人们的极大兴趣。双金属纳米颗粒由两种不同类型的金属组成,在废水中起着重要作用。双金属纳米粒子比单金属纳米粒子具有更大的表面积,增加了它们的吸附。本文研究了铋镁双金属纳米颗粒的合成、吸附行为及其对废水中重金属(镉、铅、锌)的去除效果。利用自然资源(植物提取物)合成双金属纳米颗粒具有环境友好、可靠、无毒、成本低廉等优点,比传统方法具有更重要的意义。从根、花、叶和果皮等生物质废弃物中提取的植物提取物由萜类、黄酮类和生物碱等新型次生代谢物组成,具有稳定和还原作用。利用SEM、EDX和XRD等不同技术对合成的纳米颗粒进行形貌、组成和尺寸分析。重金属的去除率取决于pH值、吸附剂用量和金属的初始浓度。结果表明,植物介导合成的纳米颗粒可以作为一种高效的吸附剂去除废水中的重金属。
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