{"title":"Mechanochemical Interaction of Phenylboronic Acid with Polyphenylsilsesquioxane and a Hydroxy(phenyl)siloxane Oligomer","authors":"V. V. Libanov, A. A. Kapustina, N. P. Shapkin","doi":"10.1134/S1811238223700388","DOIUrl":null,"url":null,"abstract":"<p>The interaction of phenylboronic acid with polyphenylsiloxane and a hydroxy(phenyl)siloxane oligomer has been studied. For the first time, phenylboronic acid was used as a starting material for the production of polyboronphenylsiloxanes under conditions of mechanochemical activation. It has been established that the main side processes induced by activation are abstraction of the phenyl substituent from the boron atom, formation of biphenyl, and trimerization of phenylboronic acid. Since boron compounds (including phenylboronic acid) have biological activity, their introduction into the polymer chain will make it possible to obtain materials with useful properties. For example, boron-containing polymers can be used as coatings to protect against insect vectors of various diseases. The work is fundamental in nature and contributes to revealing and understanding the mechanisms of mechanochemical modification of organosilicon polymers.</p>","PeriodicalId":740,"journal":{"name":"Polymer Science, Series C","volume":"65 2","pages":"173 - 179"},"PeriodicalIF":1.6000,"publicationDate":"2023-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer Science, Series C","FirstCategoryId":"1","ListUrlMain":"https://link.springer.com/article/10.1134/S1811238223700388","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
引用次数: 0
Abstract
The interaction of phenylboronic acid with polyphenylsiloxane and a hydroxy(phenyl)siloxane oligomer has been studied. For the first time, phenylboronic acid was used as a starting material for the production of polyboronphenylsiloxanes under conditions of mechanochemical activation. It has been established that the main side processes induced by activation are abstraction of the phenyl substituent from the boron atom, formation of biphenyl, and trimerization of phenylboronic acid. Since boron compounds (including phenylboronic acid) have biological activity, their introduction into the polymer chain will make it possible to obtain materials with useful properties. For example, boron-containing polymers can be used as coatings to protect against insect vectors of various diseases. The work is fundamental in nature and contributes to revealing and understanding the mechanisms of mechanochemical modification of organosilicon polymers.
期刊介绍：
Polymer Science, Series C (Selected Topics) is a journal published in collaboration with the Russian Academy of Sciences. Series C (Selected Topics) includes experimental and theoretical papers and reviews on the selected actual topics of macromolecular science chosen by the editorial board (1 issue a year). Submission is possible by invitation only. All journal series present original papers and reviews covering all fundamental aspects of macromolecular science. Contributions should be of marked novelty and interest for a broad readership. Articles may be written in English or Russian regardless of country and nationality of authors. All manuscripts are peer reviewed
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