Safety and quality of natural bee honey produced under different trademarks as sold in supermarkets

V. Lyasota, N. Bogatko, N. Bukalova, V. Dzmil, O. Hitska, T. Mazur, S. Tkachuk, T. Prilipko, B. Vakula
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Abstract

Against the background of the globalization of economic relations between countries, the activation of international trade is becoming urgent. In view of this, one of the main tasks for Ukraine as a member of the WTO and in connection with the prospect of its accession to the EU is the harmonization of national regulatory and legal requirements with international ones in the field of food safety and quality. The purpose of the research is to assess the safety and quality of honey of various types of individual domestic producers and to develop express, efficient methods for determining the quality of honey using the POCKET-PAL-3 refractometer and the safety of honey for establishing its adulteration with sodium hydrogen carbonate, alkaline detergents using indicators, as well as beet sugar by microscopy. The object of the study was the assessment of organoleptic, physico-chemical, microbiological parameters of natural bee honey of different botanical origins and varieties and detection of its adulteration, which was sold in supermarkets from various domestic manufacturers under the following trademarks. Analytical, organoleptic, physicochemical, microbiological, radiological, statistical methods of research were used to implement the research goal. Honey produced by different manufacturers according to organoleptic indicators: appearance, color, consistency, smell and taste, met the requirements of DSTU 4497:2005, except for sample №. 3, in which a discrepancy in taste was found. At the same time, according to physical and chemical parameters, honey samples №. 1, 2, 4 and 5 met the requirements of DSTU 4497:2005, except for sample №. 3 - by mass fraction of sucrose (to anhydrous substance) - 6.48±0.04 %, which did not meet the requirements of the current DSTU, the increase was 8.00 %. According to microbiological parameters and specific activity of Cs-137, it was established that all honey samples met the requirements of the national standard of Ukraine (DSTU 4497:2005). Tests were conducted to detect the adulteration of honey with sodium bicarbonate using the bromocresol green indicator, alkaline detergents using the chrome dark blue indicator, and beet sugar adulteration. For the express determination of the qualitative indicator - the mass fraction of honey, we used the POCKET-PAL-3 refractometer (Poland) for the first time. So, for the first time, we used the POCKET-PAL-3 refractometer (Poland) for the express determination of the mass fraction of water, which provides an opportunity to determine the mass fraction of dry matter with the subsequent calculation of the mass fraction of water, which ensures the reliability of the obtained indicators in 99.9 % compared to the indicators, established using a URL refractometer (model 1) in accordance with the requirements of DSTU 4497, and for the first time, patented methods of establishing the adulteration of honey with sodium bicarbonate, alkaline detergents were applied, the probability of the obtained indicators was 99.9 %, as well as adulteration with beet sugar by the microscopy method. Key words: natural honey, honey production capacity, organoleptic, physicochemical, microbiological parameters, safety, quality, consumer.
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超市销售的不同商标天然蜜蜂蜂蜜的安全性和质量
在国家间经济关系全球化的背景下,激活国际贸易已迫在眉睫。有鉴于此,乌克兰作为世贸组织成员的主要任务之一,以及与它加入欧盟的前景有关的主要任务之一,是使国家管理和法律要求与食品安全和质量领域的国际要求协调一致。本研究的目的是评估国内不同类型个体生产者生产的蜂蜜的安全性和质量,并开发快速、高效的方法,使用口袋- pal -3折光仪测定蜂蜜的质量,并通过显微镜测定蜂蜜的安全性,以确定其掺入碳酸氢钠、碱性洗涤剂和甜菜糖。本研究的目的是评估不同植物来源和品种的天然蜜蜂蜂蜜的感官、理化和微生物参数,并检测其掺假情况。采用分析学、感官学、理化、微生物学、放射学、统计学等方法进行研究。不同厂家根据感官指标生产的蜂蜜:外观,颜色,稠度,气味和味道,符合DSTU 4497:2005的要求,除了样品№。3,其中发现了味道的差异。同时,根据物理和化学参数,蜂蜜样品№。1、2、4和5符合DSTU 4497:2005的要求,除了样品№。3 -蔗糖(对无水物质)的质量分数- 6.48±0.04%,不符合现行DSTU的要求,增加了8.00 %。根据样品中Cs-137的微生物学参数和比活性测定,确定蜂蜜样品均符合乌克兰国家标准(DSTU 4497:2005)的要求。采用溴甲酚绿指示剂、铬深蓝色指示剂和甜菜糖掺假指示剂对蜂蜜进行了碳酸氢钠掺假检测。为了快速测定蜂蜜质量分数这一定性指标,我们首次使用波兰的POCKET-PAL-3折光计。因此,我们首次使用POCKET-PAL-3型折光仪(波兰)对水的质量分数进行了快速测定,为在计算水的质量分数的同时测定干物质的质量分数提供了机会,与DSTU 4497要求的URL折光仪(型号1)建立的指标相比,保证了所得指标的可靠性达到99.9%。采用专利方法建立了蜂蜜中碳酸氢钠的掺假,碱性洗涤剂,所得指标的概率为99.9%,以及用显微镜法掺假甜菜糖。关键词:天然蜂蜜,蜂蜜生产能力,感官,理化,微生物参数,安全,质量,消费者
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