N. S. Bredov, V. V. Kireev, V. A. Polyakov, I. B. Sokol’skaya, A. S. Esin
{"title":"Modern Approaches to Obtaining Organofunctional Silsesquioxanes","authors":"N. S. Bredov, V. V. Kireev, V. A. Polyakov, I. B. Sokol’skaya, A. S. Esin","doi":"10.1134/S181123822370039X","DOIUrl":null,"url":null,"abstract":"<p>Modern research in the field of synthesis of organofunctional oligosilsesquioxanes is considered. Relationships between the composition and structure of oligomeric organosilsesquioxanes and the conditions for their formation during the hydrolytic and acidohydrolytic polycondensation of organotrialkoxysilanes containing various functionalities, such as methacrylic, aminopropyl, carboxyl, and cyclotriphosphazene groups, in organic radicals bonded to silicon atoms are shown. A comparative analysis of approaches to the synthesis of organofunctional incompletely condensed oligosilsesquioxanes has been carried out.</p>","PeriodicalId":740,"journal":{"name":"Polymer Science, Series C","volume":"65 2","pages":"180 - 195"},"PeriodicalIF":1.6000,"publicationDate":"2023-10-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer Science, Series C","FirstCategoryId":"1","ListUrlMain":"https://link.springer.com/article/10.1134/S181123822370039X","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
引用次数: 0
Abstract
Modern research in the field of synthesis of organofunctional oligosilsesquioxanes is considered. Relationships between the composition and structure of oligomeric organosilsesquioxanes and the conditions for their formation during the hydrolytic and acidohydrolytic polycondensation of organotrialkoxysilanes containing various functionalities, such as methacrylic, aminopropyl, carboxyl, and cyclotriphosphazene groups, in organic radicals bonded to silicon atoms are shown. A comparative analysis of approaches to the synthesis of organofunctional incompletely condensed oligosilsesquioxanes has been carried out.
期刊介绍：
Polymer Science, Series C (Selected Topics) is a journal published in collaboration with the Russian Academy of Sciences. Series C (Selected Topics) includes experimental and theoretical papers and reviews on the selected actual topics of macromolecular science chosen by the editorial board (1 issue a year). Submission is possible by invitation only. All journal series present original papers and reviews covering all fundamental aspects of macromolecular science. Contributions should be of marked novelty and interest for a broad readership. Articles may be written in English or Russian regardless of country and nationality of authors. All manuscripts are peer reviewed
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