Investigations into the structural, morphology and optoelectronics properties of the CdO:Cu films produced by spray pyrolysis

IF 1 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Digest Journal of Nanomaterials and Biostructures Pub Date : 2023-09-20 DOI:10.15251/djnb.2023.183.1007
M. Ahmed, A. Alshahrie, E. R. Shaaban
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Abstract

This study used spray pyrolysis to create CdO films that were undoped and doped with Cu at varied concentrations (0, 1, 2, 3, 4 and 5%). The materials' polycrystalline cubic nature is confirmed by XRD examination. Rietveld refinement was used to get the lattice constant. In terms of energy dispersive more about the chemical makeup of materials. The structure, morphological, optical, and electrical properties of the film were investigated using the (XRD), (SEM), UV- spectrophotometer, and Hall arrangement. The band optical gaps, opt E g , of the CdO:Cu films were observed to decrease as the quantity of Cu doping increased. Also, effective Cu doping enhances the electrical characteristics of CdO, as shown by the film's 3 % resistivity. The carrier concentration is approximately 5x1020 of that 2.25x1020 of the undoped film, whereas the amount of Cu doping is approximately ten of that of the CdO film. To increase both optical and electrical properties in a variety of optoelectronic device applications, Cu-CdO films can be used as Transparent Conducting Oxide (TCO) materials.
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喷雾热解法制备CdO:Cu薄膜的结构、形貌及光电性能研究
本研究采用喷雾热解法制备了不同浓度(0、1、2、3、4、5%)Cu掺杂和未掺杂的CdO膜。通过XRD检测证实了材料的多晶立方性质。用Rietveld细化得到晶格常数。在能量分散方面,更多的是关于材料的化学组成。采用x射线衍射(XRD)、扫描电镜(SEM)、紫外分光光度计(UV-分光光度计)和霍尔排列法对膜的结构、形貌、光学和电学性能进行了研究。结果表明,随着Cu掺杂量的增加,CdO:Cu薄膜的能带光学隙(opt eg)减小。此外,有效的Cu掺杂提高了CdO的电学特性,如薄膜的3%电阻率所示。载流子浓度约为未掺杂膜的2.25 × 1020的5 × 1020,而Cu掺杂量约为CdO膜的10倍。为了提高各种光电子器件应用中的光学和电学性能,Cu-CdO薄膜可以用作透明导电氧化物(TCO)材料。
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来源期刊
Digest Journal of Nanomaterials and Biostructures
Digest Journal of Nanomaterials and Biostructures 工程技术-材料科学:综合
CiteScore
1.50
自引率
22.20%
发文量
116
审稿时长
4.3 months
期刊介绍: Under the aegis of the Academy of Romanian Scientists Edited by: -Virtual Institute of Physics operated by Virtual Company of Physics.
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