Nano-crystalline Sn-Co-X Alloy Alternative to Decorative Chromium Plating

Wenhua Hui , Yanhong Gu , Jiajun Liu , Fanjuan Meng , Zhijun Zhang , Yuliang Li , Zhanping Li , Lili Cao , Xiaohan Zhang
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Abstract

Decorative chromium demand in the worldwide market is more than three times that of hard chromium. However, chromium plating processes have long been known to be hazardous. The corrosion resistance of a nano-crystalline Sn-Co-X alloy as an alternative for decorative chromium has been studied. The corrosion resistance of Sn-Co-X is better than trivalent chromium, hexavalent chromium, and it is much better than coarser- grained Sn-Co alloy, our research shows. The microstructures of Sn-Co-X alloy were analyzed by SEM, TEM, XPS and AES. The mechanism of its excellent corrosion resistance is described herein.

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纳米晶Sn-Co-X合金装饰镀铬的替代品
装饰铬在世界市场上的需求量是硬铬的三倍以上。然而,镀铬工艺早就被认为是危险的。研究了一种纳米晶Sn-Co-X合金作为装饰铬替代品的耐腐蚀性能。研究表明,Sn-Co- x合金的耐腐蚀性能优于三价铬、六价铬,远优于粗晶Sn-Co合金。采用SEM、TEM、XPS和AES分析了Sn-Co-X合金的显微组织。介绍了其优异耐腐蚀性能的机理。
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