Study of the electrodeposition process of NiFE alloys from chloride electrolytes: II

M. Lieder, S. BiaŁŁozor
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Abstract

The cathodic codeposition of nickel and iron from chloride solutions with organic additives (D-mannitol, citric or ascorbic acids) has been investigated. It was found that the ratio of the concentrations of iron and nickel in the deposit was always higher that cFe2+/CNi2+ in the electrolytes irrespective of the buffer capacity of the solution. The experimental results obtained did not confirm the theory of Dahms and Croll.

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氯化物电解液电沉积NiFE合金工艺研究ⅱ
研究了含有机添加剂(d -甘露醇、柠檬酸或抗坏血酸)的氯化物溶液中镍和铁的阴极共沉积。结果表明,无论溶液的缓冲容量如何,电解液中铁和镍的浓度比始终高于cFe2+/CNi2+。得到的实验结果并不能证实达姆斯和克罗尔的理论。
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