Radiolysis of aqueous solution of cyanide ion

Qi Shengchu, Wu Jilan
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Abstract

The yields of the radiolytic products in air, N2 and N2O saturated aqueous solution of cyanide ion have been determined by combining the paper chromatographic method and carrier technique. The variations of the yields of the products in various systems have been investigated systematically by the scavenger method. The reaction kinetics of active species (OH, e-aq and H) with HCN and CN- has been investigated. The G values of radiolytic products originating from different pathway of reactions were determined. The possibility of increasing the yields of amino acids has also been studied, and a method of increasing the G value of glycine has been found

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氰化物离子水溶液的放射性溶解
采用纸层析法和载体技术相结合的方法,测定了氰化物在空气、N2和N2O饱和氰化物水溶液中辐射分解产物的产率。用清除剂法系统地研究了不同体系中产物收率的变化。研究了活性物质OH、e-aq和H与HCN和CN-的反应动力学。测定了不同反应途径产生的放射性溶解产物的G值。还研究了提高氨基酸产率的可能性,并找到了提高甘氨酸G值的方法
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