{"title":"On the Formation of Deposits during Autoclave Oxidative Leaching of Concentrates of Refractory Sulfide Gold Ores","authors":"O. D. Linnikov, A. G. Kitai, G. A. Bitkov","doi":"10.1134/S0036029523070078","DOIUrl":null,"url":null,"abstract":"<div><div><p><b>Abstract</b>—The processes occurring during autoclave oxidation leaching of refractory sulfide gold ore concentrates are discussed. As a result of them, hard-to-remove deposits (crust), which decrease the productivity of the equipment, form on all internal surfaces of autoclaves. The phase composition of the deposits is shown to change from section to section in an autoclave, and the main component of the deposits is found to be potassium jarosite KFe<sub>3</sub>(SO<sub>4</sub>)<sub>2</sub>(OH)<sub>6</sub>. The mechanism of formation of deposits is analyzed and possible methods to prevent them are discussed.</p></div></div>","PeriodicalId":769,"journal":{"name":"Russian Metallurgy (Metally)","volume":null,"pages":null},"PeriodicalIF":0.4000,"publicationDate":"2023-12-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Metallurgy (Metally)","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1134/S0036029523070078","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"METALLURGY & METALLURGICAL ENGINEERING","Score":null,"Total":0}
引用次数: 0
Abstract—The processes occurring during autoclave oxidation leaching of refractory sulfide gold ore concentrates are discussed. As a result of them, hard-to-remove deposits (crust), which decrease the productivity of the equipment, form on all internal surfaces of autoclaves. The phase composition of the deposits is shown to change from section to section in an autoclave, and the main component of the deposits is found to be potassium jarosite KFe3(SO4)2(OH)6. The mechanism of formation of deposits is analyzed and possible methods to prevent them are discussed.
期刊介绍：
Russian Metallurgy (Metally) publishes results of original experimental and theoretical research in the form of reviews and regular articles devoted to topical problems of metallurgy, physical metallurgy, and treatment of ferrous, nonferrous, rare, and other metals and alloys, intermetallic compounds, and metallic composite materials. The journal focuses on physicochemical properties of metallurgical materials (ores, slags, matters, and melts of metals and alloys); physicochemical processes (thermodynamics and kinetics of pyrometallurgical, hydrometallurgical, electrochemical, and other processes); theoretical metallurgy; metal forming; thermoplastic and thermochemical treatment; computation and experimental determination of phase diagrams and thermokinetic diagrams; mechanisms and kinetics of phase transitions in metallic materials; relations between the chemical composition, phase and structural states of materials and their physicochemical and service properties; interaction between metallic materials and external media; and effects of radiation on these materials.
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