{"title":"Metal nanoparticles decorated two-dimensional nanosheets as heterogeneous catalysts for coupling reactions","authors":"Manash R. Das, Najrul Hussain, Ritupana Duarah, Nidhi Sharma, Priyakhee Sarmah, Ashutosh Thakur, Prantika Bhattacharjee, Utpal Bora, Rabah Boukherroub","doi":"10.1080/01614940.2022.2100633","DOIUrl":null,"url":null,"abstract":"<p><b>ABSTRACT</b></p><p>This review presents a brief discussion on the numerous synthetic techniques used to prepare metal nanoparticles supported on various two-dimensional (2D) materials. Special emphasis has been given to graphene and other 2D analogues such as g-C<sub>3</sub>N<sub>4</sub>, h-BN, MoS<sub>2</sub>, WS<sub>2</sub> etc. supported metal nanoparticles. In addition to these, this review outlines the applications of the developed metal nanoparticles–2D composite materials for catalytic coupling reactions, which have recently emerged as a promising strategy in carbon–heteroatom or carbon–carbon bond formation. The effect of size and morphology of metal nanoparticles–2D composite materials on their catalytic performance toward different coupling reactions such as Suzuki, Heck, Sonogashira, etc. have been discussed in detail.</p>","PeriodicalId":50986,"journal":{"name":"Catalysis Reviews-Science and Engineering","volume":"29 3","pages":""},"PeriodicalIF":9.3000,"publicationDate":"2022-09-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"3","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Catalysis Reviews-Science and Engineering","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1080/01614940.2022.2100633","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 3
Abstract
ABSTRACT
This review presents a brief discussion on the numerous synthetic techniques used to prepare metal nanoparticles supported on various two-dimensional (2D) materials. Special emphasis has been given to graphene and other 2D analogues such as g-C3N4, h-BN, MoS2, WS2 etc. supported metal nanoparticles. In addition to these, this review outlines the applications of the developed metal nanoparticles–2D composite materials for catalytic coupling reactions, which have recently emerged as a promising strategy in carbon–heteroatom or carbon–carbon bond formation. The effect of size and morphology of metal nanoparticles–2D composite materials on their catalytic performance toward different coupling reactions such as Suzuki, Heck, Sonogashira, etc. have been discussed in detail.
期刊介绍：
Catalysis Reviews is dedicated to fostering interdisciplinary perspectives in catalytic science and engineering, catering to a global audience of industrial and academic researchers. This journal serves as a bridge between the realms of heterogeneous, homogeneous, and bio-catalysis, providing a crucial and critical evaluation of the current state of catalytic science and engineering. Published topics encompass advances in technology and theory, engineering and chemical aspects of catalytic reactions, reactor design, computer models, analytical tools, and statistical evaluations.
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