Metal nanoparticles decorated two-dimensional nanosheets as heterogeneous catalysts for coupling reactions

IF 9.3 2区 化学 Q1 CHEMISTRY, PHYSICAL Catalysis Reviews-Science and Engineering Pub Date : 2022-09-13 DOI:10.1080/01614940.2022.2100633
Manash R. Das, Najrul Hussain, Ritupana Duarah, Nidhi Sharma, Priyakhee Sarmah, Ashutosh Thakur, Prantika Bhattacharjee, Utpal Bora, Rabah Boukherroub
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引用次数: 3

Abstract

ABSTRACT

This review presents a brief discussion on the numerous synthetic techniques used to prepare metal nanoparticles supported on various two-dimensional (2D) materials. Special emphasis has been given to graphene and other 2D analogues such as g-C3N4, h-BN, MoS2, WS2 etc. supported metal nanoparticles. In addition to these, this review outlines the applications of the developed metal nanoparticles–2D composite materials for catalytic coupling reactions, which have recently emerged as a promising strategy in carbon–heteroatom or carbon–carbon bond formation. The effect of size and morphology of metal nanoparticles–2D composite materials on their catalytic performance toward different coupling reactions such as Suzuki, Heck, Sonogashira, etc. have been discussed in detail.

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金属纳米粒子修饰二维纳米片作为偶联反应的非均相催化剂
摘要本文简要介绍了用于制备金属纳米颗粒的各种二维材料的合成技术。特别强调了石墨烯和其他2D类似物,如g-C3N4, h-BN, MoS2, WS2等负载的金属纳米颗粒。除此之外,本文还概述了所开发的金属纳米颗粒-二维复合材料在催化偶联反应中的应用,这是最近在碳杂原子或碳碳键形成中出现的一种有前途的策略。详细讨论了金属纳米颗粒-二维复合材料对Suzuki、Heck、Sonogashira等不同偶联反应催化性能的影响。
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来源期刊
CiteScore
22.30
自引率
2.80%
发文量
29
期刊介绍: Catalysis Reviews is dedicated to fostering interdisciplinary perspectives in catalytic science and engineering, catering to a global audience of industrial and academic researchers. This journal serves as a bridge between the realms of heterogeneous, homogeneous, and bio-catalysis, providing a crucial and critical evaluation of the current state of catalytic science and engineering. Published topics encompass advances in technology and theory, engineering and chemical aspects of catalytic reactions, reactor design, computer models, analytical tools, and statistical evaluations.
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