Power-law patterns in the Phanerozoic sedimentary records of carbon, oxygen, sulfur, and strontium isotopes

IF 2 Journal of Palaeogeography Pub Date : 2024-01-01 Epub Date: 2023-11-28 DOI:10.1016/j.jop.2023.11.003
Haitao Shang
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Abstract

Power-law patterns appear in a variety of natural systems on the modern Earth; nevertheless, whether such behaviors appeared in the deep-time environment has rarely been studied. Isotopic records in sedimentary rocks, which are widely used to reconstruct the geological/geochemical conditions in paleoenvironments and the evolutionary trajectories of biogeochemical cycles, offer an opportunity to investigate power laws in ancient geological systems. In this study, I focus on the Phanerozoic sedimentary records of carbon, oxygen, sulfur, and strontium isotopes, which have well documented and extraordinarily comprehensive datasets. I perform statistical analyses on these datasets and show that the variations in the sedimentary records of the four isotopes exhibit power-law behaviors. The exponents of these power laws range between 2.2 and 2.9; this narrow interval indicates that the variations in carbon, oxygen, sulfur, and strontium isotopes likely belong to the same universality class, suggesting that these systematic power-law patterns are governed by universal, scale-free mechanisms. I then derive a general form for these power laws from a minimalistic model based on basic physical principles and geosystem-specific assumptions, which provides an interpretation for the power-law patterns from the perspective of thermodynamics. The fundamental mechanisms regulating such patterns might have been ubiquitous in paleoenvironments, implying that similar power-law behaviors may exist in the sedimentary records of other isotopes.

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显生宙碳、氧、硫和锶同位素沉积记录的幂律模式
幂律模式出现在现代地球的各种自然系统中;然而,这种行为是否出现在深时环境中却鲜有研究。沉积岩的同位素记录被广泛用于重建古环境的地质/地球化学条件和生物地球化学循环的演化轨迹,为研究古地质系统的幂律提供了机会。在这项研究中,我着重于显生宙的碳、氧、硫和锶同位素的沉积记录,这些同位素有很好的记录和非常全面的数据集。我对这些数据集进行了统计分析,并表明四种同位素的沉积记录的变化表现出幂律行为。这些幂律的指数在2.2到2.6之间;这个狭窄的间隔表明,碳、氧、硫和锶同位素的变化可能属于同一个普适类,这表明这些系统的幂律模式是由普适的、无标度的机制控制的。然后,我从基于基本物理原理和地球系统特定假设的极简模型中推导出这些幂律的一般形式,这从热力学的角度提供了幂律模式的解释。调节这种模式的基本机制可能在古环境中普遍存在,这意味着类似的幂律行为可能存在于其他同位素的沉积记录中。
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