Mechanical and Functional Properties of Composite Coatings with Fine Reinforcements Produced from Galvanic Processing Waste

IF 0.9 4区 材料科学 Q3 MATERIALS SCIENCE, CERAMICS Powder Metallurgy and Metal Ceramics Pub Date : 2023-11-16 DOI:10.1007/s11106-023-00386-1
D. M. Samchenko, G. A. Bagliuk, G. M. Kochetov, O. V. Lastivka, D. O. Derecha, T. O. Prikhna
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Abstract

The potential of wastewaters from the galvanic industry treated to remove toxic heavy-metal contaminants for the manufacture of commercial products lies in the development of processes for their reuse. This research addresses the feasibility of employing galvanic waste in the production of powder coatings. Powder waste generated through the resource-saving ferritic method and electroerosion dispersion method is significantly safer for the environment than that generated through reagent methods. Coatings resulting from wastewater treatment exhibit mechanical properties that meet current industry standards. The introduction of 15 wt.% spent polyvalent iron oxide sorbent into paint coatings enhances their mechanical performances. Specifically, the rebound strength increases from 20 to 40 cm/kg and tensile strength from 5 to 7.4 mm, the bending strength decreases from 8 to 5 mm, and the corrosion resistance of the coatings improves by 1.5 times compared to the standard samples. These improvements are attributed to the introduction of chemically and thermally stable crystalline phases possessing ferromagnetic properties into the coatings. As a result, these coatings increase shielding against electromagnetic radiation in the megahertz range by three times compared to the standard coatings. A significant research finding is the potential for reusing ferromagnetic waste from the galvanic industry in specialized materials.

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用电镀锌废渣制备细增强复合涂层的力学性能和功能性能
对电镀工业废水进行处理以去除有毒重金属污染物以用于制造商业产品的潜力在于开发其再利用的工艺。本研究探讨了利用电废物生产粉末涂料的可行性。通过资源节约型铁素体法和电侵蚀分散法产生的粉末废料对环境的安全性明显高于通过试剂法产生的粉末废料。废水处理后的涂料具有符合当前工业标准的机械性能。在涂料中加入15%的废多价氧化铁吸附剂,提高了涂料的机械性能。其中,涂层的回弹强度从20 ~ 40 cm/kg增加到40 cm/kg,抗拉强度从5 ~ 7.4 mm增加到5 mm,抗弯强度从8 ~ 5 mm降低到5 mm,耐腐蚀性能比标准样品提高了1.5倍。这些改进是由于在涂层中引入了具有铁磁性的化学和热稳定的晶体相。因此,与标准涂层相比,这些涂层对兆赫范围内电磁辐射的屏蔽能力提高了三倍。一项重要的研究发现是在特殊材料中重新利用来自电工业的铁磁性废物的潜力。
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来源期刊
Powder Metallurgy and Metal Ceramics
Powder Metallurgy and Metal Ceramics 工程技术-材料科学:硅酸盐
CiteScore
1.90
自引率
20.00%
发文量
43
审稿时长
6-12 weeks
期刊介绍: Powder Metallurgy and Metal Ceramics covers topics of the theory, manufacturing technology, and properties of powder; technology of forming processes; the technology of sintering, heat treatment, and thermo-chemical treatment; properties of sintered materials; and testing methods.
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