Scale-up of a peroxide-based pig slurry additive for gaseous emission reduction and downstream value retention

IF 6.1 Q2 ENGINEERING, ENVIRONMENTAL Cleaner Environmental Systems Pub Date : 2023-12-06 DOI:10.1016/j.cesys.2023.100157
Stephen Nolan , Dermot Hughes , Camilla E. Thorn , Ruairi Friel , Vincent O'Flaherty
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Abstract

Pig slurry is an agricultural residue with potential for utilisation as organic fertiliser and biomethane feedstock. That potential value is typically diminished via greenhouse and ammonia gaseous losses during temporary storage, an issue further exacerbated by the global warming, pollutant and malodorous nature of those compounds. Existing methods of reducing emissions from pig slurry may require significant capital outlay and/or may prove difficult to retrofit. A promising reactive oxygen-based additive (GasAbate®) was thus scaled-up to 1 m3 tanks filled with 750 L weaner slurry. Several experiments were carried out in three distinct phases, namely i. ambient temperature scale-up; ii. heated 1 m3 trials to determine optimal application method; iii. heated 1 m3 trials to compare results in static and dynamic chamber scenarios, with each iteration aiming to garner understanding of treatment efficacy under various conditions. The results demonstrate the scalability of this additive, its efficacy in reducing total volume of gaseous emissions (63–90% reduction), ammonia emissions (22–58% reduction) and malodorous compound evolution (22–83% reduction for a range of compounds) during temporary storage and the resulting retention of energy and nutrient value in the slurry, with 34–57% higher biomethane potential. The use of this additive could be well suited to farms that require short-term slurry storage (ca. 30 days) before feeding the slurry to a biogas system.

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扩大基于过氧化物的猪粪添加剂的规模,以减少气体排放并保持下游价值
猪粪浆是一种农业残留物,具有用作有机肥料和生物甲烷原料的潜力。这种潜在价值通常会在临时储存过程中因温室效应和氨气损失而降低,而这些化合物的全球变暖、污染和恶臭性质又进一步加剧了这一问题。现有的减少猪粪浆排放的方法可能需要大量的资金投入,并且/或者很难进行改造。因此,将一种前景看好的活性氧添加剂(GasAbate®)放大到装有 750 升断奶猪泥浆的 1 立方米储罐中。实验分三个不同阶段进行:i.常温放大;ii.加热 1 立方米试验,以确定最佳应用方法;iii.加热 1 立方米试验,以比较静态室和动态室情景下的结果,每次迭代都旨在了解各种条件下的处理效果。结果表明了这种添加剂的可扩展性、在临时储存期间减少气体排放总量(减少 63-90%)、氨排放(减少 22-58%)和恶臭化合物演变(一系列化合物减少 22-83%)方面的功效,以及由此在泥浆中保留的能量和营养价值,并将生物甲烷的潜力提高 34-57%。这种添加剂非常适合在将泥浆送入沼气系统之前需要短期储存泥浆(约 30 天)的农场。
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来源期刊
Cleaner Environmental Systems
Cleaner Environmental Systems Environmental Science-Environmental Science (miscellaneous)
CiteScore
7.80
自引率
0.00%
发文量
32
审稿时长
52 days
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