Data Mining Applied to the Electrochemical Noise Technique in the Time/Frequency Domain for Stress Corrosion Cracking Recognition

L. Calabrese, M. Galeano, E. Proverbio
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Abstract

In this paper, time/frequency domain data processing was proposed to analyse the EN signal recorded during stress corrosion cracking on precipitation-hardening martensitic stainless steel in a chloride environment. Continuous Wavelet Transform, albeit with some limitations, showed a suitable support in the discriminatory capacity among transient signals related to the different stress corrosion cracking mechanisms. In particular, the aim is to propose the analysis of electrochemical noise signals under stress corrosion cracking conditions in the time–frequency domain by using the Hilbert–Huang approach. The Hilbert–Huang Transform (performed by the Empirical Mode Decomposition approach) was finally proposed to carry out an identification of the corrosion mechanisms in comparison to conventional data processing methods. By using this approach, a detailed simultaneous decomposition of the original electrochemical noise data in the time and frequency domain was carried out. The method gave useful information about transitions among different corrosion mechanisms, allowing us to (i) identify a specific characteristic response for each corrosion damaging phenomenon induced by stress corrosion cracking, (ii) time each corrosion of the damaging phenomenon, and (iii) provide a topological description of the advancing SCC damaging stages. This characteristic evidences that the Hilbert–Huang Transform is a very powerful technique to potentially recognize and distinguish the different corrosion mechanisms occurring during stress corrosion cracking.
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将数据挖掘应用于时域/频域电化学噪声技术以识别应力腐蚀裂纹
提出了一种时频域数据处理方法,对沉淀硬化马氏体不锈钢在氯化物环境中应力腐蚀开裂过程中所记录的EN信号进行分析。连续小波变换虽然有一定的局限性,但对不同应力腐蚀开裂机制的瞬态信号的区分能力有较好的支持。特别地,目的是提出利用Hilbert-Huang方法在时频域分析应力腐蚀开裂条件下的电化学噪声信号。与传统的数据处理方法相比,最后提出了Hilbert-Huang变换(由经验模态分解方法执行)来识别腐蚀机制。利用该方法,对原始电化学噪声数据进行了时域和频域的详细同时分解。该方法提供了关于不同腐蚀机制之间转变的有用信息,使我们能够(i)确定由应力腐蚀开裂引起的每种腐蚀破坏现象的特定特征响应,(ii)确定每种腐蚀破坏现象的时间,以及(iii)提供推进SCC破坏阶段的拓扑描述。这一特征证明了Hilbert-Huang变换是一种非常强大的技术,可以识别和区分应力腐蚀开裂过程中发生的不同腐蚀机制。
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