Permeability of polymer-modified kaolinite and fly ash-kaolinite mixtures under different confining pressures and OCRs

S.-L. Li, R.-J. He, X. Kang
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Abstract

With the goal of promoting the treatment and reuse of fly ash, a series of permeability tests were conducted to investigate the hydraulic conductivity (K) of polymer (chitosan, PEO, xanthan gum)-fly ash-kaolinite systems under different confining pressures and OCRs. The addition of fly ash increased the K of kaolinite due to changes in particle size and gradation, and the effect is not significant when the fly ash content is below 30%. PEO and xanthan gum increased the K of kaolinite, with xanthan gum having a more significant effect, while chitosan reduces it. For fly ash-kaolinite mixtures, chitosan and xanthan gum had negligible impact on the K, whereas PEO increased it by an order of magnitude. In addition, confining pressure restricts the flow channel while increasing the effective contact area between polymers and soil particles. The Koc/Knc of polymer-modified kaolinite rapidly converges at high OCRs, while the that of polymer-modified fly ash-kaolinite converges at low OCRs. This study provides insight into the effects of polymer modification on the hydraulic conductivity of fly ash-clay mixtures and provides guidance for the application of polymer modification technology in soil improvement.
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不同约束压力和 OCR 条件下聚合物改性高岭石和粉煤灰-高岭石混合物的渗透性
为了促进粉煤灰的处理和再利用,在不同围压和ocr条件下,对聚合物(壳聚糖、PEO、黄原胶)-粉煤灰-高岭石体系的导流系数(K)进行了一系列渗透率试验研究。粉煤灰的掺入使高岭石的K值因粒度和级配的变化而增加,当粉煤灰掺入量低于30%时影响不显著。PEO和黄原胶均能提高高岭石的K值,其中黄原胶的作用更显著,壳聚糖的作用更低。对于粉煤灰-高岭石混合物,壳聚糖和黄原胶对K的影响可以忽略不计,而PEO对K的影响可以提高一个数量级。此外,围压限制了流动通道,同时增加了聚合物与土壤颗粒之间的有效接触面积。聚合物改性高岭石的Koc/Knc在高光照度下迅速收敛,而聚合物改性粉煤灰高岭石的Koc/Knc在低光照度下收敛。本研究揭示了聚合物改性对粉煤灰-粘土混合料导水性的影响,为聚合物改性技术在土壤改良中的应用提供了指导。
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