A comparative investigation on the decomposition of triclosan via synthesized heterogeneous nano-catalysts in the presence of peroxymonosulfate

IF 3.4 3区 化学 Q2 CHEMISTRY, PHYSICAL Catalysis Communications Pub Date : 2023-12-12 DOI:10.1016/j.catcom.2023.106820
Afshin Ebrahimi , Kun-Yi Andrew Lin , Malihe Moazeni
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Abstract

Advanced oxidation (AOPs) utilizing peroxymonosulfate (PMS) are efficient processes for the degradation of organic pollutants. This study aimed to synthesize and characterize cobalt ferrite (CoFe2O4), graphene oxide (GO), MIL-101(Fe), and their composite structures. The nanomaterials were applied as catalysts by PMS for triclosan (TCS) decomposition. The maximum removal rates of TCS were 49.29, 66.13, 84.04, 89.73, and 100% for PMS alone, CoFe2O4, GO, MIL-101(Fe), and CoFe2O4/MIL-101(Fe)/GO with PMS, respectively. Metal ions leaching declined in CoFe2O4/MIL-101(Fe)/GO/PMS compared with others. Hence, the composite nanomaterials appear to be effective catalysts for the degradation of organic pollutants by PMS activation.

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在过一硫酸盐存在下通过合成的异质纳米催化剂分解三氯生的比较研究
利用过氧单硫酸盐(PMS)的高级氧化(AOPs)是降解有机污染物的高效工艺。本研究旨在合成和表征钴铁氧体(CoFe2O4)、氧化石墨烯(GO)、MIL-101(Fe)及其复合结构。这些纳米材料被用作 PMS 催化剂,用于分解三氯生(TCS)。单用 PMS、CoFe2O4、GO、MIL-101(Fe)和 CoFe2O4/MIL-101(Fe)/GO 与 PMS 对三氯生(TCS)的最大去除率分别为 49.29、66.13、84.04、89.73 和 100%。与其他材料相比,CoFe2O4/MIL-101(Fe)/GO/PMS 的金属离子浸出率有所下降。因此,复合纳米材料似乎是 PMS 活化降解有机污染物的有效催化剂。
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来源期刊
Catalysis Communications
Catalysis Communications 化学-物理化学
CiteScore
6.20
自引率
2.70%
发文量
183
审稿时长
46 days
期刊介绍: Catalysis Communications aims to provide rapid publication of significant, novel, and timely research results homogeneous, heterogeneous, and enzymatic catalysis.
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