A. N. Usol’tsev, A. A. Sonina, N. A. Korobeinikov, S. A. Adonin
{"title":"Trimethylammonium Dichlorohexachlorotellurate(IV): Crystal Structure and Specific Features of Noncovalent Cl···Cl Interactions","authors":"A. N. Usol’tsev, A. A. Sonina, N. A. Korobeinikov, S. A. Adonin","doi":"10.1134/S1070328423600213","DOIUrl":null,"url":null,"abstract":"<p>The reaction of tellurium(IV) oxide with trimethylammonium chloride in the presence of gaseous chlorine in concentrated hydrochloric acid gives supramolecular dichlorohexachlorotellurate (Me<sub>3</sub>NH)<sub>2</sub>{[TeCl<sub>6</sub>](Cl<sub>2</sub>)} (<b>I</b>), whose structure is determined by X-ray diffraction (XRD) (CIF file CCDC no. 2217752). The data of elemental and XRD analyses suggest a restricted stability of the synthesized compound. Specific features of noncovalent Cl···Cl interactions in the crystal structure of compound <b>I</b> are studied by Raman spectroscopy.</p>","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"49 12","pages":"807 - 811"},"PeriodicalIF":1.1000,"publicationDate":"2023-12-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Coordination Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S1070328423600213","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
The reaction of tellurium(IV) oxide with trimethylammonium chloride in the presence of gaseous chlorine in concentrated hydrochloric acid gives supramolecular dichlorohexachlorotellurate (Me3NH)2{[TeCl6](Cl2)} (I), whose structure is determined by X-ray diffraction (XRD) (CIF file CCDC no. 2217752). The data of elemental and XRD analyses suggest a restricted stability of the synthesized compound. Specific features of noncovalent Cl···Cl interactions in the crystal structure of compound I are studied by Raman spectroscopy.
期刊介绍：
Russian Journal of Coordination Chemistry is a journal that publishes reviews, original papers, and short communications on all aspects of theoretical and experimental coordination chemistry. Modern coordination chemistry is an interdisciplinary science that makes a bridge between inorganic, organic, physical, analytical, and biological chemistry.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
