Heat and Mass Limitations in an Anaerobic Digestion Process

D. Sponza, Ruki̇ye Özteki̇n
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Abstract

In this study, heat and mass limitations in an anaerobic reactor containing domestic solids were researched in batch reactors. The dynamic and static anaerobic data for 365 days showed that the methane production for the dynamic digestion reactor was measured as 176.86 m3 which is extremely high for static anaerobic one (102.78 m3). As the heat transfer data increased with elevated temperature the methane productions also were highlighted. The external mass transfer was observed for easily degradable solids. In the calculation of external mass transfer during the degradation of organics dissolved with difficulty some semiempirical regressions were used. In the calculation of internal mass transfer the microorganisms in the solids were taken into consideration and the diffusion was defined with Fick's law. The diffusion coefficient D, was found to be constant. Generally, the diffusion coefficient of solids in water (Dw) was < 1.0. The effect of the total solid (TS) concentration in anaerobic batch reactors (TS between 12% and 39%) was investigated. The methane gas production decreased minorly when the TS levels elevated to 30%. At a TS percentage of 39%, the methane generation decreased significantly. At high TS, the mass transfer was inhibited and ended with lowered methane generations while the hydrolysis process did not affect significantly at high TS concentrations.
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厌氧消化过程中的热量和质量限制
本研究以间歇式反应器为基础,研究了含有生活固体的厌氧反应器中的热量和质量限制。365 天的动态和静态厌氧数据显示,动态消化反应器的甲烷产量为 176.86 立方米,而静态厌氧反应器的甲烷产量则非常高(102.78 立方米)。随着传热数据随温度升高而增加,甲烷产量也显著增加。在易降解固体中观察到了外部传质。在计算难溶解有机物降解过程中的外部传质时,使用了一些半经验回归法。在计算内部传质时,考虑了固体中的微生物,并用菲克定律定义了扩散。结果发现,扩散系数 D 是常数。一般来说,固体在水中的扩散系数(Dw)小于 1.0。研究了厌氧间歇反应器中总固体(TS)浓度(TS 在 12% 至 39% 之间)的影响。当 TS 水平升至 30% 时,甲烷气体产量略有下降。当 TS 百分比达到 39% 时,甲烷产量明显下降。在高 TS 条件下,传质受到抑制,最终导致甲烷生成量降低,而在高 TS 浓度条件下,水解过程并未受到明显影响。
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