Pyrolysis of Domestic Sewage Sludge: Effect of Process Parameters on Biochar Calorific Value

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2023-12-01 DOI:10.2478/cee-2023-0058
H. Al-Hamaiedeh, S. Aljbour, T. El-Hasan, Tuqa Almrayat, Ziad Al-Ghazawi
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Abstract

Abstract This research aims to look into a sustainable technique for the treatment, reuse and disposal of domestic sewage sludge (DSS). The purpose of the study was to examine the operating factors that influence the calorific value of the produced biochar from the pyrolysis of DSS. Based on the analysis of the full factorial design, the impacts of the pyrolysis conditions, specifically: temperature, heating rate, and isothermal time on the calorific value of biochar were evaluated. When the pyrolysis temperature was raised from 300 to 500 oC, the calorific value of biochar was decreased by 34%. A 14% decrease in the calorific content of the biochar was also noticed when the heating rate was increased from 5 to 35 oC/min. When the isothermal time was increased from 45 to 120 minutes, the calorific value of the biochar remained essentially unchanged. No interaction effects among process variables were found using the factorial design methodology. A first-order regression model was developed to predict the calorific value of biochar using the magnitude of the effects of the process factors and their interactions. The model predictions agreed very well with the obtained experimental results.
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热解生活污水污泥:工艺参数对生物炭热值的影响
摘要 本研究旨在探讨一种处理、再利用和处置生活污水污泥(DSS)的可持续技术。研究的目的是考察影响热解 DSS 产生的生物炭热值的操作因素。根据全因子设计分析,评估了热解条件,特别是温度、加热速率和等温时间对生物炭热值的影响。当热解温度从 300 摄氏度升至 500 摄氏度时,生物炭的热值降低了 34%。当加热速度从 5 oC/min 提高到 35 oC/min 时,生物炭的热值也降低了 14%。当等温时间从 45 分钟增加到 120 分钟时,生物炭的热值基本保持不变。使用因子设计方法没有发现工艺变量之间的交互效应。利用工艺因素及其相互作用的影响大小,建立了一个一阶回归模型来预测生物炭的热值。模型预测结果与实验结果非常吻合。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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