Oxidation of Alcohols to Aldehydes and Ketones Using a Catalytic Pairing of a Nitroxide and Nitric Acid

IF 2 Q2 CHEMISTRY, ORGANIC SynOpen Pub Date : 2023-12-21 DOI:10.1055/a-2217-9577
Manisha Sharma, Arturo León Sandoval, Nicholas E. Leadbeater
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Abstract

A methodology for the oxidation of alcohols to aldehydes and ketones is presented. The approach employs catalytic quantities of a nitroxide and nitric acid, with no additives or metal catalysts being required. It proves effective for a range of aromatic, heteroaromatic, and aliphatic alcohol substrates, the desired products being formed in good to excellent yield. In the case of primary alcohols, the oxidation can be stopped at the aldehyde without concomitant formation of the corresponding carboxylic acid.

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利用氧化氮和硝酸的催化配对将醇氧化成醛和酮
本文介绍了一种将醇氧化成醛和酮的方法。该方法使用催化量的硝基氧化物和硝酸,无需添加剂或金属催化剂。事实证明,这种方法对一系列芳香族、杂芳香族和脂肪族醇类底物都很有效,所形成的所需产物收率良好甚至极高。对于伯醇,氧化可以在醛中停止,而不会同时生成相应的羧酸。
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SynOpen
SynOpen CHEMISTRY, ORGANIC-
CiteScore
2.30
自引率
4.00%
发文量
35
审稿时长
6 weeks
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