Application of Soy Lecithin as a Promoter of Methane Hydrate Formation

IF 0.8 4区 化学 Q4 CHEMISTRY, MULTIDISCIPLINARY Doklady Chemistry Pub Date : 2023-12-25 DOI:10.1134/S001250082360075X
V. P. Mel’nikov, N. S. Molokitina, A. O. Drachuk, K. A. Pletneva, A. A. Kibkalo, B. V. Grigor’ev, G. Pandey
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Abstract

The course towards active development of the Arctic zone of the Russian Federation by fuel-and-energy companies involves the development of new methods and approaches to the storage and transportation of natural gas to reduce the negative impact on the ecosystems of cold regions while maintaining the economic feasibility of their use. This work proposes a method for optimizing the technology for transporting and storing natural gas in the form of gas hydrates using soy lecithin as a promoting additive. Experimental methods showed that the addition of soy lecithin to a concentration of 0.5 wt % is on a par with the most efficient promoter of hydrate formation—the surfactant sodium dodecyl sulfate at a concentration of 0.1 wt %. However, a comparison of environmental characteristics demonstrates a clear advantage of soy lecithin. In addition, it was demonstrated that the synthesis of methane hydrate from ground frozen solutions of soy lecithin is at least three times faster than that from liquid solutions.

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应用大豆卵磷脂作为甲烷水合物形成的促进剂
摘要 俄罗斯联邦燃料和能源公司积极开发北极地区的过程中,需要开发新的天然气储存和运输方法和途径,以减少对寒冷地区生态系统的负面影响,同时保持天然气使用的经济可行性。这项工作提出了一种方法,利用大豆卵磷脂作为促进添加剂,优化以天然气水合物形式运输和储存天然气的技术。实验方法表明,添加浓度为 0.5 wt % 的大豆卵磷脂与最有效的水合物形成促进剂--浓度为 0.1 wt % 的表面活性剂十二烷基硫酸钠不相上下。不过,对环境特性的比较表明,大豆卵磷脂具有明显的优势。此外,研究还表明,从大豆卵磷脂的地面冷冻溶液中合成甲烷水合物的速度比从液体溶液中合成甲烷水合物的速度至少快三倍。
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来源期刊
Doklady Chemistry
Doklady Chemistry 化学-化学综合
CiteScore
1.20
自引率
12.50%
发文量
7
审稿时长
6-12 weeks
期刊介绍: Doklady Chemistry is a journal that publishes new research in chemistry and chemical engineering of great significance. Initially the journal was a forum of the Russian Academy of Science and published only best contributions from Russia in the form of short articles. Now the journal welcomes submissions from any country in the English or Russian language. Every manuscript must be recommended by Russian or foreign members of the Russian Academy of Sciences.
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