Research progress of Prussian blue and its analogues for cathodes of aqueous zinc ion batteries

IF 10.7 2区 材料科学 Q1 CHEMISTRY, PHYSICAL Journal of Materials Chemistry A Pub Date : 2024-01-01 DOI:10.1039/D3TA06641J
Jiayi Liu, Zhongrong Shen and Can-Zhong Lu
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Abstract

Aqueous zinc-ion batteries (AZIBs) have garnered significant attention for large-scale applications due to their low cost, safety, and eco-friendliness. Among all cathode materials, Prussian blue and its analogues (PBAs) have garnered significant attention and been subjected to extensive research due to their diverse property-effectiveness, simple synthesis process, reversible Zn2+ insertion/removal capability, and other notable characteristics. However, numerous studies have revealed that the utilization of PBAs as a cathode material in AZIBs still presents certain challenges, including limited energy density and prolonged structural instability during cycling. In light of the aforementioned opportunities and challenges for PBAs, we conducted a comprehensive literature review encompassing synthesis, analysis of energy storage mechanisms, enhancement of electrolyte–electrode interfaces, and battery applications. The objective of this review is to encourage active engagement from researchers interested in AZIBs and PBA cathode materials, thereby fostering research and industrialization efforts that collectively contribute towards the advancement of safe and environmentally friendly energy storage.

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用于锌离子水电池阴极的普鲁士蓝及其类似物的研究进展
含水锌离子电池(AZIBs)因其低成本、安全性和环保性而在大规模应用中备受关注。在所有阴极材料中,普鲁士蓝及其类似物(PBAs)因其不同的性能、功效、简单的合成过程、可逆的 Zn2+ 插入/去除能力以及其他显著特点而备受关注,并得到了广泛的研究。然而,大量研究表明,将 PBA 用作 AZIB 的阴极材料仍面临着一些挑战,包括能量密度有限和循环过程中结构长期不稳定。鉴于 PBAs 面临的上述机遇和挑战,我们进行了一次全面的文献综述,内容包括合成、储能机制分析、电解质-电极界面的增强以及电池应用。本综述旨在鼓励对 AZIBs 和 PBAs 正极材料感兴趣的研究人员积极参与,从而促进研究和产业化工作,共同为推动安全、环保的能源存储做出贡献。
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来源期刊
Journal of Materials Chemistry A
Journal of Materials Chemistry A CHEMISTRY, PHYSICAL-ENERGY & FUELS
CiteScore
19.50
自引率
5.00%
发文量
1892
审稿时长
1.5 months
期刊介绍: The Journal of Materials Chemistry A, B & C covers a wide range of high-quality studies in the field of materials chemistry, with each section focusing on specific applications of the materials studied. Journal of Materials Chemistry A emphasizes applications in energy and sustainability, including topics such as artificial photosynthesis, batteries, and fuel cells. Journal of Materials Chemistry B focuses on applications in biology and medicine, while Journal of Materials Chemistry C covers applications in optical, magnetic, and electronic devices. Example topic areas within the scope of Journal of Materials Chemistry A include catalysis, green/sustainable materials, sensors, and water treatment, among others.
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