Enhanced electrochemical performance of Bi2O3 via facile synthesis as anode material for ultra-long cycle lifespan lithium-ion batteries

Abstract

The urgent demand for stable electrode materials, especially for the anode, arises in the pursuit of high-energy Li-ion batteries. This research focuses on bismuth oxide (Bi₂O₃) and uncovers its performance through a straightforward, commercially viable synthesis route, along with the optimization of binders and electrolytes. By employing a sodium carboxymethyl cellulose binder and fluoroethylene carbonate additives, the Bi₂O₃ anode demonstrates significantly enhanced performance compared to prior studies. It attains an impressive initial capacity of approximately 750 mA h g⁻¹, exhibits excellent rate capability at 1000 mA g⁻¹ and maintains stable cycling performance over 6000 cycles.