Muzammil Hussain , Anam Saddique , Kamakshaiah Charyulu Devarayapalli , Bolam Kim , In Woo Cheong , Dae Sung Lee
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引用次数: 0
Abstract
The integral part of covalent organic frameworks (COFs) is covalent bonds. Thus, stable and functional links must be developed to expand the potential applications of COFs. Herein, in situ linkage functionalization using a three-component irreversible Doebner reaction was achieved to fabricate chemically stable carboxylic acid-bearing COFs (Tp-Tta-COOH and Tp-Tapb-COOH), which have abundant chelating groups and ordered electron donor–acceptor moieties facilitating charge separation for effective Cr(VI) adsorption and photoreduction, respectively. These functionalized COFs are more effective at Cr(VI) removal via adsorption and photoreduction than their unfunctionalized counterparts (Tp-Tta and Tp-Tapb). The synergy of adsorption and photocatalysis is crucial to effectively remove Cr(VI) from aqueous solutions. This synergy empowers Tp-Tta-COOH to be used continuously for Cr(VI) removal without any elution after each cycle. Furthermore, Tp-Tta-COOH exhibits high chemical stability, durability, and recyclability. This study will promote the development of durable and useful COF materials for real-world applications.
期刊介绍:
Applied Catalysis B: Environment and Energy (formerly Applied Catalysis B: Environmental) is a journal that focuses on the transition towards cleaner and more sustainable energy sources. The journal's publications cover a wide range of topics, including:
1.Catalytic elimination of environmental pollutants such as nitrogen oxides, carbon monoxide, sulfur compounds, chlorinated and other organic compounds, and soot emitted from stationary or mobile sources.
2.Basic understanding of catalysts used in environmental pollution abatement, particularly in industrial processes.
3.All aspects of preparation, characterization, activation, deactivation, and regeneration of novel and commercially applicable environmental catalysts.
4.New catalytic routes and processes for the production of clean energy, such as hydrogen generation via catalytic fuel processing, and new catalysts and electrocatalysts for fuel cells.
5.Catalytic reactions that convert wastes into useful products.
6.Clean manufacturing techniques that replace toxic chemicals with environmentally friendly catalysts.
7.Scientific aspects of photocatalytic processes and a basic understanding of photocatalysts as applied to environmental problems.
8.New catalytic combustion technologies and catalysts.
9.New catalytic non-enzymatic transformations of biomass components.
The journal is abstracted and indexed in API Abstracts, Research Alert, Chemical Abstracts, Web of Science, Theoretical Chemical Engineering Abstracts, Engineering, Technology & Applied Sciences, and others.