Diazinon degradation in water applying glow discharge plasma technology

IF 1.5 4区 工程技术 Q3 ENGINEERING, CHEMICAL Brazilian Journal of Chemical Engineering Pub Date : 2024-01-04 DOI:10.1007/s43153-023-00427-7
Francisco E. Rodrigues, Fabiano A. N. Fernandes
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Abstract

Pesticides are chemical compounds widely used in crop pest control, ensuring high productivity and product quality control. However, pesticides are toxic and can be bioaccumulative. Their excessive use causes environmental and health impacts. In this study, the potential of glow discharge plasma to degrade diazinon present in water was investigated. For the degradation process, a glow discharge plasma (GDP) system was used to process diazinon at several plasma flow rates (10, 20, and 30 mL/min) and exposure times (10, 20, and 30 min). The degradation levels and the identification of the by-products were analyzed by gas chromatography coupled to mass spectrum (GC-MS). GDP processing efficiently degraded diazinon, reaching a maximum potential degradation of 8.19 ± 0.92 mg/L, sufficient to bring diazinon-contaminated waters to safe levels. Two parallel degradation routes were proposed for diazinon degradation by cold plasma.

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利用辉光放电等离子体技术降解水中的二嗪农
农药是广泛用于作物虫害防治的化合物,可确保高生产率和产品质量控制。然而,杀虫剂具有毒性和生物累积性。过量使用会对环境和健康造成影响。本研究调查了辉光放电等离子体降解水中二嗪农的潜力。在降解过程中,使用了辉光放电等离子体(GDP)系统,以不同的等离子体流速(10、20 和 30 mL/min)和暴露时间(10、20 和 30 分钟)处理二嗪农。通过气相色谱-质谱联用(GC-MS)分析了降解水平和副产物的鉴定。GDP 处理可有效降解二嗪农,最大降解潜力为 8.19 ± 0.92 mg/L,足以使受二嗪农污染的水域达到安全水平。提出了冷等离子体降解二嗪农的两种平行降解途径。
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来源期刊
Brazilian Journal of Chemical Engineering
Brazilian Journal of Chemical Engineering 工程技术-工程:化工
CiteScore
2.50
自引率
0.00%
发文量
84
审稿时长
6.8 months
期刊介绍: The Brazilian Journal of Chemical Engineering is a quarterly publication of the Associação Brasileira de Engenharia Química (Brazilian Society of Chemical Engineering - ABEQ) aiming at publishing papers reporting on basic and applied research and innovation in the field of chemical engineering and related areas.
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