Numerical Study on Heat Generation Characteristics of Charge and Discharge Cycle of the Lithium-Ion Battery

Abstract

Lithium-ion batteries are the backbone of novel energy vehicles and ultimately contribute to a more sustainable and environmentally friendly transportation system. Taking a 5 Ah ternary lithium-ion battery as an example, a two-dimensional axisymmetric electrochemical–thermal coupling model is developed via COMSOL Multiphysics 6.0 in this study and then is validated with the experimental data. The proportion of different types of heat generation in a 26,650 ternary lithium-ion battery during the charge/discharge cycle is investigated numerically. Moreover, the impact of essential factors such as charge/discharge multiplier and ambient temperature on the reaction heat, ohmic heat, and polarization heat are analyzed separately. The numerical results indicate that the total heat generated by the constant discharge process is the highest in the charging and discharging cycle of a single battery. The maximum heat production per unit volume is 67,446.99 W/m3 at 2 C multiplier discharge. Furthermore, the polarization heat presents the highest percentage in the charge/discharge cycle, reaching up to 58.18% at 0 C and 1 C multiplier discharge. In a high-rate discharge, the proportion of the reaction heat decreases from 34.31% to 12.39% as the discharge rate increases from 0.5 C to 2 C. As the discharge rate rises and the ambient temperature falls, the maximum temperature increase of the single-cell battery also rises, with a more pronounced impact compared to increasing the discharge rate.